Basic information Safety Supplier Related

(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)

Basic information Safety Supplier Related

(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Basic information

Product Name:
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
Synonyms:
  • 1,1'-BIS(2-NAPHTHOL) DITRIFLATE
  • 1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULPHONATE)
  • 1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
  • 1,1-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
  • 1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE)
  • (R)-(-)-1,1`-Bi-2-naphthyl bis(trifluoromethanesulphonate)
  • (R)1,1'-BINAPHTHALENE-2,2'-DIYL BIS(TRI- FLUOROMETHANESULF.)
  • (R)-(-9-1,1'-BINAPHTHYL-2,2'-DIYL BIS-(TRIFLUOROMETHANESULFONATE)
CAS:
126613-06-7
MF:
C22H12F6O6S2
MW:
550.45
Product Categories:
  • API intermediates
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry
  • BINOL Series
  • Chiral Oxygen
Mol File:
126613-06-7.mol
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(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Chemical Properties

Melting point:
83-85 °C(lit.)
alpha 
-149 º (c=1, CHCl3)
Boiling point:
578.8±50.0 °C(Predicted)
Density 
1.5402 (estimate)
storage temp. 
Sealed in dry,Room Temperature
form 
Powder
color 
White
optical activity
[α]23/D 146°, c = 1 in chloroform
Water Solubility 
Insoluble
Sensitive 
moisture sensitive
BRN 
4282753
CAS DataBase Reference
126613-06-7(CAS DataBase Reference)
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Safety Information

Hazard Codes 
C,Xi
Risk Statements 
34
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10-21
Hazard Note 
Irritant
HazardClass 
8
PackingGroup 
II
HS Code 
29072990

MSDS

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(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Usage And Synthesis

Chemical Properties

white powder

Uses

(R)-(?)-1,1′-Bi-2-naphthol bis(trifluoromethanesulfonate) can be used:

  • In the synthesis of heterobidentate ligands for asymmetric catalysis.
  • To prepare 2-(diphenylphosphino)-2′-alkoxy-1,1′-binaphthyls by reacting with bis(aryl) phosphonic acids.
  • As a starting material for the synthesis of binaphthyl based rhodium catalysts used in the hydrogenation of styrene.

(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)Supplier

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