(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Basic information
- Product Name:
- (R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
- Synonyms:
-
- 1,1'-BIS(2-NAPHTHOL) DITRIFLATE
- 1,1'-BINAPHTHYL-2,2'-DIYL BIS(TRIFLUOROMETHANESULPHONATE)
- 1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
- 1,1-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE)
- 1,1'-BI-2-NAPHTHOL-BIS(TRIFLUOROMETHANESULPHONATE)
- (R)-(-)-1,1`-Bi-2-naphthyl bis(trifluoromethanesulphonate)
- (R)1,1'-BINAPHTHALENE-2,2'-DIYL BIS(TRI- FLUOROMETHANESULF.)
- (R)-(-9-1,1'-BINAPHTHYL-2,2'-DIYL BIS-(TRIFLUOROMETHANESULFONATE)
- CAS:
- 126613-06-7
- MF:
- C22H12F6O6S2
- MW:
- 550.45
- Product Categories:
-
- API intermediates
- Asymmetric Synthesis
- Synthetic Organic Chemistry
- BINOL Series
- Chiral Oxygen
- Mol File:
- 126613-06-7.mol
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(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Chemical Properties
- Melting point:
- 83-85 °C(lit.)
- alpha
- -149 º (c=1, CHCl3)
- Boiling point:
- 578.8±50.0 °C(Predicted)
- Density
- 1.5402 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- form
- Powder
- color
- White
- optical activity
- [α]23/D 146°, c = 1 in chloroform
- Water Solubility
- Insoluble
- Sensitive
- moisture sensitive
- BRN
- 4282753
- InChI
- InChI=1S/C22H12F6O6S2/c23-21(24,25)35(29,30)33-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)34-36(31,32)22(26,27)28/h1-12H
- InChIKey
- OYJLCOSEYYZULE-UHFFFAOYSA-N
- SMILES
- C1(=C(OS(=O)(=O)C(F)(F)F)C=CC2C=CC=CC1=2)C1C(OS(=O)(=O)C(F)(F)F)=CC=C2C=CC=CC=12
- CAS DataBase Reference
- 126613-06-7(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- C,Xi
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45-27
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- Hazard Note
- Irritant
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29072990
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
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(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate) Usage And Synthesis
Chemical Properties
white powder
Uses
(R)-(?)-1,1′-Bi-2-naphthol bis(trifluoromethanesulfonate) can be used:
- In the synthesis of heterobidentate ligands for asymmetric catalysis.
- To prepare 2-(diphenylphosphino)-2′-alkoxy-1,1′-binaphthyls by reacting with bis(aryl) phosphonic acids.
- As a starting material for the synthesis of binaphthyl based rhodium catalysts used in the hydrogenation of styrene.
(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)Supplier
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(R)-(-)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)(126613-06-7)Related Product Information
- Levofloxacin Methylate
- Trifluoromethanesulfonic anhydride
- Pefloxacin mesylate
- COPPER(II) TRIFLUOROMETHANESULFONATE
- YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
- Trifluoromethanesulfonic acid
- Gabexate mesylate
- (S)-(-)-1,1'-Bi-2-naphthol
- Lithium trifluoromethanesulfonate
- Sodium trifluoromethanesulfonate
- 1,1'-Bi-2-naphthol
- Danofloxacin mesylate
- Scandium trifluoromethanesulfonate
- (R)-(+)-1,1'-Bi-2-naphthol
- (S)-(+)-1,1'-Binaphthol-2,2'-bis(trifluoromethanesulfonate)
- Trifluoromethane
- 1,1'-BINAPHTHYL
- Methyl trifluoromethanesulfonate