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1,2-PHENYLENE PHOSPHOROCHLORIDATE

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1,2-PHENYLENE PHOSPHOROCHLORIDATE Basic information

Product Name:
1,2-PHENYLENE PHOSPHOROCHLORIDATE
Synonyms:
  • 3,2-benzodioxaphosphole,2-chloro-2-oxide
  • o-Phenylenephosphorochloridate
  • 2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE 2-OXIDE
  • 1,2-PHENYLENE PHOSPHOROCHLORIDATE, TECH.
  • 1,2-PHENYLENE PHOSPHOROCHLORIDATE
  • 1,2-PHENYLENE CHLOROPHOSPHATE
  • 2-Chloro-1,3,2-benzodioxaphosphole 2-oxide, o-Phenylene chlorophosphate
  • o-Phenylene chlorophosphate
CAS:
1499-17-8
MF:
C6H4ClO3P
MW:
190.52
EINECS:
216-106-7
Mol File:
1499-17-8.mol
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1,2-PHENYLENE PHOSPHOROCHLORIDATE Chemical Properties

Melting point:
56-62 °C
Boiling point:
120 °C9 mm Hg(lit.)
Density 
1.57±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
BRN 
142368
EPA Substance Registry System
1,3,2-Benzodioxaphosphole, 2-chloro-, 2-oxide (1499-17-8)
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Safety Information

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
10
HazardClass 
8
PackingGroup 
III

MSDS

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1,2-PHENYLENE PHOSPHOROCHLORIDATE Usage And Synthesis

Uses

Reactant for preparation of:

  • Uridine diphosphate-glucose derivatives as potential chain terminators of β-glucan biosynthesis with antifungal activity
  • Vinyloxy phosphorus monomers

  • Phosphorylation agent

Purification Methods

After distilling it in a vacuum, it sets to a colourless solid. It is soluble in pet ether, *benzene and slightly soluble in Et2O. [Khwaja et al. J Chem Soc (C) 2092 1970, Anschütz & Broeker Justus Liebigs Ann Chem 454 109 1927, Beilstein 6 IV 5602.]

1,2-PHENYLENE PHOSPHOROCHLORIDATESupplier

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