1-ACETOXY-1-CYANOETHYLENE
1-ACETOXY-1-CYANOETHYLENE Basic information
- Product Name:
- 1-ACETOXY-1-CYANOETHYLENE
- Synonyms:
-
- 1-Cyanovinyl ester of acetic acid
- 1-Kyanvinylester kyseliny octove
- 1-kyanvinylesterkyselinyoctove
- 2-(acetyloxy)-2-propenenitril
- 2-(acetyloxy)-2-propenenitrile
- 2-hydroxy-acrylonitrilacetate
- 2-hydroxy-acrylonitrilacetate(ester)
- 2-Hydroxyacrylonitrile acetate
- CAS:
- 3061-65-2
- MF:
- C5H5NO2
- MW:
- 111.1
- EINECS:
- 221-303-6
- Product Categories:
-
- Nitrogen Compounds
- Organic Building Blocks
- Building Blocks
- C1 to C5
- Chemical Synthesis
- Cyanides/Nitriles
- Mol File:
- 3061-65-2.mol
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1-ACETOXY-1-CYANOETHYLENE Chemical Properties
- Boiling point:
- 80-82 °C30 mm Hg(lit.)
- Density
- 1.061 g/mL at 20 °C(lit.)
- vapor pressure
- 30 mm Hg ( 80 °C)
- refractive index
- n20/D 1.426(lit.)
- Flash point:
- 147 °F
- storage temp.
- Sealed in dry,2-8°C
- solubility
- sol most organic solvents other than pure hydrocarbons.
- form
- clear liquid
- color
- Colorless to Light yellow
- BRN
- 1751158
- CAS DataBase Reference
- 3061-65-2(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- T
- Risk Statements
- 23/24/25-41-37/38
- Safety Statements
- 36/37/39-45-26
- RIDADR
- UN 3276 6.1/PG 2
- WGK Germany
- 3
- RTECS
- AG4550000
- HS Code
- 2926.90.5050
- HazardClass
- 6.1(a)
- PackingGroup
- II
- Toxicity
- skn-rbt 10 mg/24H open MLD AIHAAP 23,95,62
MSDS
- Language:English Provider:SigmaAldrich
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1-ACETOXY-1-CYANOETHYLENE Usage And Synthesis
Reactivity Profile
1-cyanovinyl acetate is a ketene equivalent for use in the Diels-Alder reaction; undergoes other cycloaddition reactions; reacts with nucleophiles and radicals[1].
Safety Profile
Poison by inhalation, ingestion, andskin contact. A skin irritant. Whenheated to decomposition it emits toxic fumes of NOx andCN-.
storage
Handling, Storage, and Precautions: highly toxic; use only in a fume hood. Reagent can be absorbed through the skin. Always wear gloves when handling this reagent.
References
1. Ranganathan, S.; Ranganathan, D.; Mehrotra, A. K. S 1977, 289.
2. Brown, D. S.; Paquette, L. A. JOC 1992, 57, 4512.
3. Nowak, R. M. JOC 1963, 28, 1182.
1-ACETOXY-1-CYANOETHYLENESupplier
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