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FLUOROIMIDE

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FLUOROIMIDE Basic information

Product Name:
FLUOROIMIDE
Synonyms:
  • 3,4-DICHLORO-1-(4-FLUORO-PHENYL)-PYRROLE-2,5-DIONE
  • FLUOROIMIDE
  • OTAVA-BB BB7014250005
  • 2,3-dichloro-n-4-fluorophenylmaleimide
  • 3,4-dichloro-1-(4-fluorophenyl)-1h-pyrrole-2,5-dione
  • 3,4-dichloro-1-(4-fluorophenyl)-1h-pyrrole-5-dione
  • mk23
  • n-p-fluorophenyl-2,3-dichloromaleimide
CAS:
41205-21-4
MF:
C10H4Cl2FNO2
MW:
260.05
Mol File:
41205-21-4.mol
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FLUOROIMIDE Chemical Properties

Melting point:
238~242℃
Boiling point:
324.7±42.0 °C(Predicted)
Density 
1.63±0.1 g/cm3(Predicted)
vapor pressure 
3.4 x 10-3 Pa (25 °C)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Sparingly), Methanol (Slightly)
form 
Solid
Water Solubility 
5.9 mg l-1 (20 °C)
pka
-4.79±0.60(Predicted)
color 
Off-White to Light Yellow
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Safety Information

Hazard Codes 
T,N
Risk Statements 
23-41-51/53
Safety Statements 
26-39-45-61
RIDADR 
UN2811 - class 6.1 - PG 3 - EHS - Toxic solids, organic, n.o.s., HI: all
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FLUOROIMIDE Usage And Synthesis

Chemical Properties

yellow crystalline powder

Uses

Fluoroimide is used to control Monilinia mali and Mycosphaerella pomi in apples, Diaporthe citri and Elsinoe fawcetti in citrus, Corticium spp. in rubber trees, Botryfis cinerea and Peronospora destructor in onions, Colletotrichum theae-sinensis and Exobasidium vexans in tea, Phytophthora infestans in potatoes at 2-5 kg a.i. ha-1 and Cercospora kaki and Mycosphaerella mwae in persimmons at 0.5-2 kg ha-1.

Definition

ChEBI: A maleimide that is substituted at positions 3 and 4 by chlorines and on the nitrogen by a p-fluorophenyl group. Previously used as a fungicide (now obsolete).

Metabolic pathway

Fluoroimide is a relatively volatile solid with a high melting point. It degrades to a range of products in soils and plants. The main pathways are hydrolysis of the amide bond causing scission of the maleimide ring and stepwise reduction involving dechlorination of the maleimide ring. Little transformation of the parent fungicide occurred on plants.

Degradation

Hydrolysis of fluoroimide is base catalysed. The DT50 values for the hydrolysis are 52.9,7.5 and 1.4 minutes at pH 3,7 and 8, respectively. The fungicide is stable to sunlight (PM).

FLUOROIMIDESupplier

Shanghai Zhixin Chemical Technology Co., Ltd.
Tel
021-60441077 18701958033
Email
shzxchem@163.com
Aikon International Limited
Tel
025-66113011 18112977050
Email
cb6@aikonchem.com
Shanghai He Huan Chemical Co., Ltd.
Tel
021-60345187 13917602471
Email
lzz841106@aliyun.com
Zhengzhou Ruke Biological Co., Ltd.
Tel
15981811963
Email
1410472904@qq.com
Zhengzhou Acme Chemical Co., Ltd.
Tel
0371-037163312495,13303845143 13303845143
Email
3001379618@qq.com