ChemicalBook > Product Catalog > Catalyst and Auxiliary > Precious Metal Catalysts > Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Basic information
- Product Name:
- Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)
- Synonyms:
-
- Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II), 98%
- Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladiuM(II),98%
- Cinnamylpalladium chloride dimer
- PalladiuM(II)(pi-cinnaMyl) Chloride DiMer
- PalladiuM(II)(π-cinnaMyl) Chloride DiMer
- PalladiuM(pi-cinnaMyl) chloride diMer 97%
- Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propenyl]dipalladium(Ⅱ)
- Di-μ-chlorobis[(1,2,3-η)-1-phenyl-2-propen-1-yl]dipalladium
- CAS:
- 12131-44-1
- MF:
- C18H12Cl2Pd2
- MW:
- 512.03
- EINECS:
- 234-579-8
- Product Categories:
-
- Pd
- Mol File:
- 12131-44-1.mol
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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Chemical Properties
- Melting point:
- 218-220°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystal
- color
- yellow
- Sensitive
- air sensitive
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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II) Usage And Synthesis
Application
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(ii) is an important organic regant for the use of transition-metal-mediated organic syntheses. It can be used as a catalyst for the ammonia cross-coupling reactions to synthesize arylamines and conversion of aryl triflates to fluorides.
Reaction
- Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds.
- Precursor for the preparation of a palladium catalyst used in the Buchwald-Hartwig amination of (hetero)aryl chlorides.
- Precursor for the preparation of a palladium catalyst used in the arylative dearomatization of phenols.
- Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines , conversion of aryl triflates to aryl fluorides , and the α-arylation of aldehydes .
Uses
Palladium(π-cinnamyl) chloride dimer can be used as a catalyst for the:
- Ammonia cross-coupling reactions to synthesize arylamines.
- Conversion of aryl triflates to fluorides.
It can also be used as a source of palladium in the asymmetric α-arylation of amides.
Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)Supplier
Shaanxi Rock New Materials Co., Ltd. Gold
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- 917-917-8888777 18691746767
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J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
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TCI (Shanghai) Development Co., Ltd.
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- 021-67121386
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ShangHai DEMO Chemical Co.,Ltd
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- 400-021-7337 2355568890
- sales@demochem.com
BeiJing Hwrk Chemicals Limted
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- 0757-86329057 18501085097
- sales3.gd@hwrkchemical.com
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Di-chlorobis[(1,2,3-)-1-phenyl-2-propenyl]dipalladium(II)(12131-44-1)Related Product Information
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