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NORCAMPHOR

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NORCAMPHOR Basic information

Product Name:
NORCAMPHOR
Synonyms:
  • (1S,4R)-bicyclo[2.2.1]heptan-2-one
  • 2,5-methanocyclohexanone
  • 2-oxonorbornane
  • Bicyclo[2.2.1]heptane-2-one
  • Norcampher
  • 2-NORCAMPHOR
  • (+/-)-2-NORBORNANONE
  • 2-NORBORNANONE
CAS:
497-38-1
MF:
C7H10O
MW:
110.15
EINECS:
207-846-1
Mol File:
497-38-1.mol
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NORCAMPHOR Chemical Properties

Melting point:
93-96 °C(lit.)
Boiling point:
168-172 °C(lit.)
Density 
0.9023 (rough estimate)
refractive index 
1.4800 (estimate)
Flash point:
93 °F
storage temp. 
Flammables area
form 
Adhering Crystals
color 
Colorless to white
Water Solubility 
Insoluble in water. Soluble in methanol.
BRN 
1209657
InChI
InChI=1S/C7H10O/c8-7-4-5-1-2-6(7)3-5/h5-6H,1-4H2
InChIKey
KPMKEVXVVHNIEY-UHFFFAOYSA-N
SMILES
C12CC(CC1)CC2=O
LogP
0.892 (est)
CAS DataBase Reference
497-38-1(CAS DataBase Reference)
EPA Substance Registry System
Bicyclo[2.2.1]heptan-2-one (497-38-1)
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Safety Information

Hazard Codes 
F
Risk Statements 
11
Safety Statements 
16-33
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
3
RTECS 
RB7680000
TSCA 
Yes
HazardClass 
4.1
PackingGroup 
III
HS Code 
29142900
Toxicity
LD50 ivn-mus: 180 mg/kg CSLNX* NX#04039

MSDS

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NORCAMPHOR Usage And Synthesis

Chemical Properties

colorless to white adhering crystals

Uses

Norcamphor is used as a building block in organic synthesis. It is also used as a precursor to norborneols.

Safety Profile

Poison by intravenous route.When heated to decomposition it emits acrid smoke andirritating fumes.

Purification Methods

Crystallise it from water and sublime it in vacuo. It has at max 287nm (EtOH). The semicarbazone has m 196-196.5o (from EtOH/H2O). The 2,4-dinitrophenylhydrazone has m 137-138o (from EtOH). [Wildman & Hemminger J Org Chem 17 1641 1952, Wood & Roberts J Org Chem 23 1124 1957, Bixter & Niemann J Org Chem 23 742 1958, Beilstein 7 III 243, 7 IV 139.]

NORCAMPHORSupplier

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