Basic information Safety Supplier Related

4-PHENYLAZO-1-NAPHTHYLAMINE

Basic information Safety Supplier Related

4-PHENYLAZO-1-NAPHTHYLAMINE Basic information

Product Name:
4-PHENYLAZO-1-NAPHTHYLAMINE
Synonyms:
  • 4-(phenylazo)-1-naphthalenamin
  • 4-[(E)-Phenyldiazenyl]-1-naphthalenamine
  • 4-Benzeneazo-1-naphthylamine
  • 4-Benzene-azo-alpha-naphthylamine
  • CI NO 11350
  • BENZENEAZO-1-NAPHTHYLAMINE
  • AURORA KA-7777
  • 4-(phenyldiazenyl)naphthalen-1-amine
CAS:
131-22-6
MF:
C16H13N3
MW:
247.29
EINECS:
205-018-4
Product Categories:
  • Azo
Mol File:
131-22-6.mol
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4-PHENYLAZO-1-NAPHTHYLAMINE Chemical Properties

Melting point:
124°C
Boiling point:
380.33°C (rough estimate)
Density 
1.1633 (rough estimate)
refractive index 
1.6470 (estimate)
solubility 
Solubility Virtually insoluble in water; slightly soluble in ethanol; soluble in acetone, benzene,ethyl acetate, toluene, xylene
Colour Index 
11350
pka
2.70(at 25℃)
form 
crystals
color 
Dark red
PH Range
Red (3.7) to yellow (5.0)
λmax
439nm
Major Application
Display device, semiconductor, sensors, photosensitive materials, recording materials, fooding materials, imaging materials, inks, engraving coatings, lubricants, hair dyes, food storage, dental materials
CAS DataBase Reference
131-22-6(CAS DataBase Reference)
EPA Substance Registry System
1-Naphthalenamine, 4-(phenylazo)- (131-22-6)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
QJ0360000
HS Code 
2927.00.5000
Toxicity
mma-sat 500 mg/plate AEMIDF 42,641,81
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4-PHENYLAZO-1-NAPHTHYLAMINE Usage And Synthesis

Preparation

aniline diazotization, and Naphthalen-1-amine coupling.

Safety Profile

Mutation data reported. When heated to decomposition it emits toxic vapors of NOx.

Purification Methods

Crystallise the dye from cyclohexane or aqueous EtOH. [Brode et al. J Am Chem Soc 74 4641 1952, Beilstein 16 H 361, 16 III 406, 16 IV 546.]

Properties and Applications

brilliant red light yellow to brilliant yellow orange (mineral oil). Red acicular crystal, melting point 123 ℃. Soluble in alcohol and benzene. In concentrated sulfuric acid for magenta; After dilution for red light brown, precipitation, At 2% hot hydrochloric acid solution for magenta solution, there are residues. Dye alcohol solution to join concentrated sodium hydroxide solution for yellow brown. Used for oil, paraffin wax, paint color.

Standard Light Fastness Heat-resistant(℃) Water Sodium Carbonate(5%) Hydrochloric acid(5%)
Melting point Stable
ISO Well 109 75 Insoluble No change Poor

4-PHENYLAZO-1-NAPHTHYLAMINE Preparation Products And Raw materials

Raw materials

4-PHENYLAZO-1-NAPHTHYLAMINESupplier

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