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1H,1H,2H,2H-PERFLUOROOCTYLTRIMETHOXYSILANE

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1H,1H,2H,2H-PERFLUOROOCTYLTRIMETHOXYSILANE Basic information

Product Name:
1H,1H,2H,2H-PERFLUOROOCTYLTRIMETHOXYSILANE
Synonyms:
  • Perfluorooctyltrimethoxysilane
  • trimethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane
  • 1H,1H,2H,2H-PERFLUOROOCTYLTRIMETHOXYSILANE
  • (TRIDECAFLUORO-1,1,2,2-TETRAHYDROOCTYL)TRIMETHOXYSILANE
  • 1H,1H,2H,2H-Perfluorooctyltrimethoxysilane 97%
  • 1H,1H,2H,2H-Perfluorooctyltrimethoxysilane97%
  • trimethoxytridecafluorooctylsilane
  • 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-(trimethoxysilyl)octane
CAS:
85857-16-5
MF:
C11H13F13O3Si
MW:
468.28
EINECS:
288-657-1
Product Categories:
  • silicone additives
Mol File:
85857-16-5.mol
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1H,1H,2H,2H-PERFLUOROOCTYLTRIMETHOXYSILANE Chemical Properties

Melting point:
<0°C
Boiling point:
88 °C
Density 
1.457
vapor pressure 
13Pa at 25℃
refractive index 
1.335
Flash point:
>65°C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
color 
Colorless to Almost colorless
Specific Gravity
1.457
Water Solubility 
240ng/L at 20℃
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
LogP
5.8 at 20℃
CAS DataBase Reference
85857-16-5(CAS DataBase Reference)
EPA Substance Registry System
Trimethoxy((perfluorohexyl)ethyl)silane (85857-16-5)
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Safety Information

Hazard Codes 
C,Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
RIDADR 
3265
Hazard Note 
Corrosive
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29319090
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1H,1H,2H,2H-PERFLUOROOCTYLTRIMETHOXYSILANE Usage And Synthesis

Chemical Properties

liquid

Uses

1H,1H,2H,2H-Perfluorooctyltrimethoxysilane, a functional material widely used to make material surface water-repellent[1]. Fluorosilane 1H,1H,2H,2H-perfluorooctyltrimethoxysilane could be coated onto the surface of BaTiO3 nanofibers by chemical reaction, which enhances their dispersion in poly(vinylidene fluoride) matrix[2].

Flammability and Explosibility

Non flammable

Synthesis

1H,1H,2H,2H-Perfluorooctyltrimethoxysilane (PFOT) could be synthesized by a two-step method: after the hydrosilylation of trichlorosilane and 1H,1H,2H-perfluoro-1-octene (HPFO), the resulting product was then subjected to the alcoholic reaction with sodium methoxide to get the PFOT[1]. 

References

[1] Xianhong Zhang . "High dielectric constant and low dielectric loss hybrid nanocomposites fabricated with ferroelectric polymer matrix and BaTiO3 nanofibers modified with perfluoroalkylsilane." Applied Surface Science 305 (2014): Pages 531-538.
[2] Feihong Ye. "Effect of reaction conditions on one-step preparation of 1H,1H,2H,2H-Perfluorooctyltrimethoxysilane by catalytic hydrosilylation over RuCl3·3H2O catalysts." Journal of Industrial and Engineering Chemistry 110 (2022): Pages 405-413.

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