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N-Benzylideneaniline

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N-Benzylideneaniline Basic information

Product Name:
N-Benzylideneaniline
Synonyms:
  • p-Benzylideneaniline
  • Phenyl-[1-phenyl-meth-(E)-ylidene]-amine
  • trans-N-Benzylideneaniline
  • Aniline, N-benzylidene-
  • Benzaldehyde anil
  • Benzenamine,N-(phenylmethylene)-
  • Benzylidene-phenyl-amine
  • N-(Phenylmethylene)benzenamine
CAS:
538-51-2
MF:
C13H11N
MW:
181.23
EINECS:
208-694-9
Product Categories:
  • B
  • Stains and Dyes
  • Stains&Dyes, A to
Mol File:
538-51-2.mol
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N-Benzylideneaniline Chemical Properties

Melting point:
52-54 °C(lit.)
Boiling point:
bp760 300°
Density 
d450 1.045
refractive index 
1.6118 (estimate)
Flash point:
>230 °F
form 
Crystalline Powder
pka
3.23±0.30(Predicted)
color 
Pale yellow
Water Solubility 
Soluble in water (partly), methanol, chloroform, alcohol, and acetic anhydride.
Merck 
14,1138
InChIKey
UVEWQKMPXAHFST-SDNWHVSQSA-N
CAS DataBase Reference
538-51-2(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, N-(phenylmethylene)-(538-51-2)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HS Code 
2921490090

MSDS

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N-Benzylideneaniline Usage And Synthesis

Uses

N-Benzylideneaniline is an additional stain which is used in various immunoassays including flow cytometry, immunofluorescense, immunohistochemistry, and other applications.

Synthesis Reference(s)

Journal of the American Chemical Society, 113, p. 4871, 1991 DOI: 10.1021/ja00013a024
Chemical and Pharmaceutical Bulletin, 23, p. 2654, 1975 DOI: 10.1248/cpb.23.2654
Tetrahedron Letters, 35, p. 6567, 1994 DOI: 10.1016/S0040-4039(00)78274-8

Purification Methods

It is steam volatile and crystallises from *benzene or 85% EtOH. The picrate has m 159o. [Beilstein 12 H 195, 12 I 169, 12 II 113, 12 III 319, 12 IV 311.]

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