Vinylferrocene Chemical Properties

Melting point:

51-53 °C (lit.)

Boiling point:

80-85 °C/0.2 mmHg (lit.)

Flash point:

144 °F

storage temp. 

Sealed in dry,2-8°C

form 

crystal

color 

orange

Water Solubility 

Insoluble in water.

Hydrolytic Sensitivity

4: no reaction with water under neutral conditions

Exposure limits

ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3

Stability:

Stable. Highly flammable. Incompatible with strong acids, strong oxidizing agents.

NIST Chemistry Reference

Vinylferrocene(1271-51-8)

Safety Information

Hazard Codes 

F

Risk Statements 

11-22

Safety Statements 

16-22-24/25-7/9-33

RIDADR 

UN 1325 4.1/PG 2

WGK Germany 

3

F 

10

TSCA 

No

HazardClass 

4.1

PackingGroup 

II

HS Code 

29319090

MSDS

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Vinylferrocene Usage And Synthesis

Chemical Properties

crystalline solid

Uses

Used in the synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides.

Definition

ChEBI: Ferrocene substituted on one of the cyclopentadienyl rings by a vinyl group.

Purification Methods

Dissolve vinylferrocene in Et2O, wash it with H2O and brine, dry (Na2SO4), and evaporate to a small volume. Purify it through an Al2O3 (Spence grade H) column by eluting the yellow band with pet ether (b 40-60o). The low melting orange crystals can be sublimed. The tetracyanoethylene adduct crystallises from *C6H6/pentane and has m 137-139o(dec). [Horspool & Sutherland Can J Chem 46 3453 1968, Berger et al. J Org Chem 39 377 1974, Rauch & Siegel J Organomet Chem 11 317 1968, Beilstein 16 III 1787.]

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