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Vinylferrocene

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Vinylferrocene Basic information

Product Name:
Vinylferrocene
Synonyms:
  • Ferrocene, ethenyl-
  • VINYLFERROCENE
  • Vinylferroceneorangextl
  • Vinylferrocene,98%
  • Vinylferrocene ,97%
  • Vinylferrocene**CUSTOMSYNTHESISPLEASEASK**
  • Vinylferrocene,99%
  • Vinylferrocene 97%
CAS:
1271-51-8
MF:
C12H12Fe10*
MW:
212.07
EINECS:
215-041-1
Product Categories:
  • metallocene
  • Classes of Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Metallocenes
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
Mol File:
1271-51-8.mol
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Vinylferrocene Chemical Properties

Melting point:
51-53 °C (lit.)
Boiling point:
80-85 °C/0.2 mmHg (lit.)
Flash point:
144 °F
storage temp. 
Sealed in dry,2-8°C
form 
crystal
color 
orange
Water Solubility 
Insoluble in water.
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
Stability:
Stable. Highly flammable. Incompatible with strong acids, strong oxidizing agents.
NIST Chemistry Reference
Vinylferrocene(1271-51-8)
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Safety Information

Hazard Codes 
F
Risk Statements 
11-22
Safety Statements 
16-22-24/25-7/9-33
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
3
10
TSCA 
No
HazardClass 
4.1
PackingGroup 
II
HS Code 
29319090

MSDS

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Vinylferrocene Usage And Synthesis

Chemical Properties

crystalline solid

Uses

Used in the synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides.

Definition

ChEBI: Ferrocene substituted on one of the cyclopentadienyl rings by a vinyl group.

Purification Methods

Dissolve vinylferrocene in Et2O, wash it with H2O and brine, dry (Na2SO4), and evaporate to a small volume. Purify it through an Al2O3 (Spence grade H) column by eluting the yellow band with pet ether (b 40-60o). The low melting orange crystals can be sublimed. The tetracyanoethylene adduct crystallises from *C6H6/pentane and has m 137-139o(dec). [Horspool & Sutherland Can J Chem 46 3453 1968, Berger et al. J Org Chem 39 377 1974, Rauch & Siegel J Organomet Chem 11 317 1968, Beilstein 16 III 1787.]

Vinylferrocene Preparation Products And Raw materials

Raw materials

VinylferroceneSupplier

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