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Ethyltriphenylphosphonium acetate

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Ethyltriphenylphosphonium acetate Basic information

Product Name:
Ethyltriphenylphosphonium acetate
Synonyms:
  • ethyltriphenyl-phosphoniuacetate
  • Phosphonium,ethyltriphenyl-,acetate
  • ETHYLTRIPHENYLPHOSPHONIUM ACETATE
  • ETHYLTRIPHENYLPHOSPHONIUM ACID ACETATE
  • ETTPPAAC
  • ethyl Triphenyl Phosphonium Acetate 65% solution
  • ETHYLTRIPHENYLPHOSPHONIUM ACETATE, 70% IN METHANOL
  • ETHYL TRIPHENYL PHOSPHONIUM ACETATE 65% IN ETHANOL
CAS:
35835-94-0
MF:
C22H23O2P
MW:
350.39
EINECS:
252-743-7
Mol File:
35835-94-0.mol
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Ethyltriphenylphosphonium acetate Chemical Properties

Boiling point:
275℃[at 101 325 Pa]
Density 
1.05
vapor pressure 
0Pa at 25℃
Flash point:
-17°(0°F)
form 
Liquid
color 
Yellow to dark brown
Water Solubility 
Soluble in water, alcohol.
Exposure limits
ACGIH: TWA 200 ppm; STEL 250 ppm (Skin)
OSHA: TWA 200 ppm(260 mg/m3)
NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3)
LogP
-0.64 at 23.5℃
CAS DataBase Reference
35835-94-0(CAS DataBase Reference)
EPA Substance Registry System
Phosphonium, ethyltriphenyl-, acetate (35835-94-0)
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Safety Information

RIDADR 
UN1993
TSCA 
Yes
HazardClass 
3
PackingGroup 
II

MSDS

  • Language:English Provider:ALFA
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Ethyltriphenylphosphonium acetate Usage And Synthesis

Description

Ethyltriphenylphosphonium Acetate, also known as ETPAAC, ETPAACc and TEPA, is a colourless to slightly yellow liquid with the chemical formula C22H23O2P. This quaternary phosphonium salt is available in a 70% by-weight solution in methanol. Notably, one mole of acetic acid is bound to each mole of ETPAAC. Furthermore, the material is mainly used for advancing and curing phenolic-based epoxy resins and serving as a phase transfer catalyst. Compared to amines, imidazoles, and quaternary ammonium salts, Ethyltriphenylphosphonium Acetate has considerably better latency and thermal stability. Further, it offers a low odour, minimal colour formation and controlled reactivity.

Uses

Ethyltriphenylphosphonium acetate is mainly used to advance and cure phenolic-based epoxy resins and as a phase transfer catalyst. It exhibits considerably better latency and thermal stability when compared to amines, imidazoles and quaternary ammonium salts. Furthermore, it has minimal odour, colour formation, and controlled reactivity. It decreases or eliminates side reactions and creates longer, straighter chain epoxy molecules with sharp molecular weight distribution.

Precautions

Store Ethyltriphenylphosphonium Acetate in a cool, dry, and well-ventilated area to ensure compliance with legal requirements. Keep ETPAAC away from heat sources and oxidizing agents to maintain safety and stability.

Ethyltriphenylphosphonium acetate Preparation Products And Raw materials

Raw materials

Ethyltriphenylphosphonium acetateSupplier

Hangzhou Molot Chemical Technology Co., Ltd. Gold
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