Bismuth(III) trifluoromethanesulfonate Chemical Properties

Melting point:

300 °C

storage temp. 

Inert atmosphere,Room Temperature

solubility 

Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.

form 

Liquid

color 

Clear colorless

Sensitive 

Hygroscopic

Hydrolytic Sensitivity

5: forms reversible hydrate

Stability:

hygroscopic

InChIKey

HIYUMYXSGIKHHE-UHFFFAOYSA-M

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-24/25

WGK Germany 

3

Hazard Note 

Irritant

TSCA 

No

HazardClass 

8

HS Code 

29049090

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Bismuth(III) trifluoromethanesulfonate Usage And Synthesis

Uses

Bismuth(III) trifluoromethanesulfonate is powerful Lewis acid useful in a number of catalytic reactions. 

Chemical Properties

White powder

Uses

Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.

Uses

Catalyzes direct substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carbamates, and carboxamides.

Uses

Catalyst for organic syntheses.

Bismuth(III) trifluoromethanesulfonate(88189-03-1)Related Product Information

• BISMUTH 2-ETHYLHEXANOATE
• Bismuth
• Bis(tributyltin) oxide
• Sodium trifluoromethanesulfinate
• YTTERBIUM(III) TRIFLATE HYDRATE, 99.90%
• BISMUTH TITANATE
• Triphenylbismuth
• Bismuth nitrate pentahydrate
• Bismuth trioxide
• BISMUTH SULFIDE
• BISMUTH NEODECANOATE
• Bismuth trichloride
• BISMUTH(III) FLUORIDE
• BISMUTH ACETATE
• BISMUTH(III) IODIDE
• BISMUTH TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE)
• BISMUTH TELLURIDE
• BISMUTH(III) BROMIDE