Product Identification

Product Name

2,4'-Dichloroacetophenone

Synonyms

1-(4-Chlorophenyl)-2-chloroethanone
2,4'-Dichloroacetophenone
4-Chlorophenacyl chloride
Chloromethyl 4-chlorophenyl ketone

CAS

937-20-2

Formula

C8H6Cl2O

Molecular Weight

189.04

EINECS

213-323-9

Beilstein/Gmelin

637861

Beilstein Reference

4-07-00-00644

Physical and Chemical Properties

Appearance

Slightly yellow solid.

Solubility in water

Insoluble

Melting Point

98

Boiling Point

270

Vapor Pressure

0.007 (25 C)

Partition Coefficient

2.79

Heat Of Vaporization

50.8 kJ/mol

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

The toxicological properties of this substance have not been fully investigated.

Inhalation

Causes respiratory tract irritation. Inhalation of dust may cause respiratory tract irritation.

Skin

No information regarding skin irritation and other potential effects was found.

Eyes

No information regarding eye irritation and other potential effects was found.

EC Risk Phrase

R 36/37/38

EC Safety Phrase

S 26 36/37/39

UN (DOT)

3335

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

119

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Stability and Reactivity

Stability

No data.

Incompatibilities

Strong oxidizing agents.

Decomposition

Hydrogen chloride, carbon monoxide, carbon dioxide.

Transport Information

UN Number

3335