Product Identification

Product Name

(2R,3S,4R,5R)-2-(Hydroxymethyl)oxane-2,3,4,5-tetrol

Synonyms

(2R,3S,4R,5R)-2-(Hydroxymethyl)oxane-2,3,4,5-tetrol
d-Fructose
Fructosteril
Fruit sugar
Frutabs

CAS

7660-25-5

Formula

C6H12O6

Molecular Weight

180.18

RTECS

LS7000000

RTECS Class

Tumorigen; Natural Product

Beilstein/Gmelin

1423189

Beilstein Reference

4-01-00-04402

Physical and Chemical Properties

Appearance

White crystalline powder. Odorless.

Solubility in water

Soluble

Melting Point

104

Boiling Point

401

Vapor Pressure

4E-8 (25 C)

Density

800 g/L

pKa/pKb

11.52 (pKa)

Partition Coefficient

-.38

Heat Of Vaporization

75.4 kJ/mol

Heat Of Combustion

-2812 kJ/mol

Usage

Foodstuffs, medicine, preservative.

Refractive Index

1.5101 (108 C)

First Aid Measures

Ingestion

Even though a substance may be considered non-toxic for the amount ingested or packaged, it should not be considered as non-toxic in any amounts. Even ingestions of various foodstuffs can cause adverse symptoms if large amounts are eaten (green apples, garlic, onion). The most important fact to remember is to treat the patient not the poison, especially when the diagnosis is unknown. Knowing that the product is listed as non-toxic helps avoid overtreating the patient or being over zealous in getting a patient to professional medical care. If there is a question of simultaneous ingestion of a product which may be more dangerous, the management on the more toxic agent should be consulted.

Inhalation

Although inhalation of common dust may not be considered toxic, it is certainly a hazard if there is inhalation of too many particles. Individuals should be removed from exposure to too high a concentration of even relatively non-toxic substances.

Skin

Foreign materials spilled on the skin may not represent a toxic or irritation hazard in small quantities, but may produce adverse effects if applied in large quantities or if used over a significant period of time. Whenever possible, foreign materials should be removed from the skin with simple washing. Should skin irritation or erythema occur, a patient may wish to seek medical assistance.

Eyes

Foreign materials in the eye may not cause a toxic reaction, but injury from a foreign body may occur. In such cases, the patient should be observed for eye irritation and should seek medical assistance if the irritation becomes significant.

Handling and Storage

Storage

Store at room temperature and 50% relative humidity for best handling characteristics. Conveying and handling equipment should be grounded. Avoid sources of ignition where fine dusts are produced.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Inhalation

Inhalation of dust may be irritating to upper respiratory tract.

Exposure Controls/Personal Protection

Personal Protection

Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.

Respirators

Wear a dust mask if dust is a nuisance.

Fire Fighting Measures

Flash Point

196

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.

Accidental Release Measures

Small spills/leaks

Clean up personnel should wear suitable protective clothing. Sweep up spilled material into containers for later disposal. Wash down spill site with water.

Stability and Reactivity

Stability

Stable at normal temperature and pressure.

Incompatibilities

Strong oxidizing agents.

Decomposition

Oxides of carbon.