Product Identification

Product Name

1-Chlorododecane

Synonyms

1-Chlorododecane
Diglycolic acid anhydride
Diglycolic anhydride
Dodecylchloride
Oxydiacetic anhydride
p-Dioxane-2,6-dione

CAS

112-52-7

CAS

4480-83-5

Formula

C12H25Cl

Formula

C4H4O4

Molecular Weight

204.79

Molecular Weight

116.07

EINECS

203-981-5

EINECS

224-761-5

Beilstein/Gmelin

112527

Beilstein/Gmelin

635778

Beilstein Reference

4-01-00-00501

Beilstein Reference

5-19-05-00005

EC Class

irritant

Physical and Chemical Properties

Appearance

Clear colorless oily liquid.

Appearance

White crystalline powder.

Solubility in water

Very soluble

Solubility in water

7 mg/L

Melting Point

-9

Melting Point

91 - 93

Boiling Point

240

Boiling Point

260

Vapor Pressure

0.02 (25 C)

Vapor Pressure

0.035 (25 C)

Density

0.867 g/cm3 (20 C)

Partition Coefficient

-2.06

Partition Coefficient

6.81

Heat Of Vaporization

47.8

Heat Of Vaporization

47.9 kJ/mol

Vapor Density

4

Refractive Index

1.4434 (20 C)

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.

Ingestion

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Inhalation

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.

Skin

Causes skin irritation. The toxicological properties of this material have not been fully investigated.

Skin

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Eyes

Causes eye irritation.

Handling and Storage

Storage

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Storage

Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Corrosives area.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.

Handling

Avoid contact with eyes, skin, and clothing. Do not breathe dust, vapor, mist, or gas. Use only in a chemical fume hood.

Hazards Identification

Ingestion

Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.

Ingestion

May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea.

Inhalation

May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. May cause abdominal pain, nausea, vomiting, and inflammation of the gums and mouth.

Skin

Causes skin burns.

Eyes

Causes eye burns. Lachrymator. Lachrymator.

EC Risk Phrase

R 36/37/38

EC Risk Phrase

R 38

EC Safety Phrase

S 26 36

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Personal Protection

Eyes: Wear chemical goggles and a face shield if splashing is possible. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Poison Class

4

Fire Fighting Measures

Flash Point

104

Flash Point

106

Autoignition

190

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Do NOT use water directly on fire. Use carbon dioxide or dry chemical.

Fire Potential

This chemical is combustible.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.

Stability and Reactivity

Stability

No data.

Incompatibilities

Oxidizing agents.

Stability

Stable at room temperature in closed containers under normal storage and handling conditions.

Incompatibilities

Water, oxidizing agents, strong bases.

Disposal Code

2

Decomposition

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Decomposition

Hydrogen chloride, carbon monoxide, carbon dioxide.

Transport Information

HS Code

2903 19 80

HS Code

2918 90 90