Product Identification

Product Name

2-Nitrodiphenyl

Synonyms

1-Nitro-2-phenylbenzene
2-Nitro-1,1'-biphenyl
2-Nitrobiphenyl

CAS

86-00-0

Formula

C12H9NO2

Molecular Weight

199.21

EINECS

201-646-8

RTECS

DV5530000

RTECS Class

Agricultural Chemical and Pesticide; Mutagen

Merck

12,6689

Beilstein/Gmelin

1818699

Beilstein Reference

4-05-00-01823

Physical and Chemical Properties

Appearance

Gold to tan crystals or brown solid.

Solubility in water

Insoluble

Melting Point

36

Boiling Point

320

Vapor Pressure

0.00045 (25 C)

Density

1.44 g/cm3

Partition Coefficient

3.52

Heat Of Vaporization

54.5 kJ/mol

Usage

Plasticizer for resins, cellulose acetate and nitrate, polystyrenes.

First Aid Measures

Ingestion

DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician.

Inhalation

IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.

Skin

IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

Eyes

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Ingestion

Harmful if swallowed.

Inhalation

Harmful if inhaled. May cause respiratory tract irritation.

Skin

May cause skin irritation. Harmful if absorbed through the skin.

Eyes

May cause irritation.

Exposure Controls/Personal Protection

Personal Protection

Wear appropriate safety goggles, protective clothing and gloves.

Respirators

Wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.

Poison Class

4

Fire Fighting Measures

Flash Point

151

Autoignition

180

Fire Fighting

Fires involving this compound can be controlled using a dry chemical, carbon dioxide or Halon extinguisher.

Fire Potential

This compound is combustible.

Accidental Release Measures

Small spills/leaks

Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Stability and Reactivity

Incompatibilities

If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation.

Stability

No data.