Product Identification

Product Name

(Acetylcyclopentadienyl)cyclopentadienyliron

Synonyms

1-Acetylferrocene
Acetoferrocene
Acetylferrocene
Ferrocene, acetyl-
Ferrocenyl methyl ketone
Iron, (acetylcyclopentadienyl)cyclopentadienyl-

CAS

1271-55-2

Formula

C12H12FeO

Molecular Weight

228.08

EINECS

215-043-2

RTECS

OB3700000

RTECS Class

Other

Beilstein/Gmelin

NA

EC Class

very toxic

Physical and Chemical Properties

Appearance

Brown to orange solid.

Solubility in water

Insoluble

Melting Point

84 - 85

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container.

Handling

Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Minimize dust generation and accumulation. Do not get on skin or in eyes. Do not ingest or inhale.

Hazards Identification

Ingestion

May be fatal if swallowed. Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.

Inhalation

Harmful if inhaled. May cause respiratory tract irritation.

Skin

Causes skin irritation. Harmful if absorbed through the skin.

Eyes

May cause eye irritation.

Hazards

Contact with metals may evolve flammable hydrogen gas.

EC Risk Phrase

R 20/21 28

EC Safety Phrase

S 22 28 36/37 45

UN (DOT)

2811

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Fire Potential

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal.

Stability and Reactivity

Disposal Code

9

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents and strong reducing agents.

Decomposition

Carbon monoxide, carbon dioxide.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2811

Hazard Class

6.1

Packing Group

I; II; III

HS Code

2931 00 95