Product Identification

Product Name

2-Chloroacetamide

Synonyms

alpha-Chloroacetamide
Benzenesulfonic acid, tridecyl-, sodium salt
Conoco C 650
Sodium 4-tridecylbenzenesulfonate

CAS

79-07-2

CAS

26248-24-8

Formula

C19H32O3S.Na

Formula

C2H4ClNO

Molecular Weight

93.51

Molecular Weight

363.52

EINECS

201-174-2

EINECS

247-536-3

RTECS

AB5075000

RTECS Class

Mutagen

Merck

13,2127

Beilstein/Gmelin

8476213

Beilstein/Gmelin

878191

Beilstein Reference

4-02-00-00490

EC Index Number

616-036-00-0

EC Class

Toxic for reproduction Category 3; Toxic; Sensitising

Physical and Chemical Properties

Appearance

Yellow to colorless crystals with a characteristic odor.

Solubility in water

980 g/L (20 C)

Melting Point

115 - 117

Boiling Point

256

Vapor Pressure

0.016 (25 C)

Density

1.60 g/cm3 (20 C)

Partition Coefficient

-.85

Heat Of Vaporization

49.4 kJ/mol

Heat Of Combustion

-1016 kJ/mol

Usage

Surface-active agent in home laundry, cleaning products & household formulated cleaners, other indust uses (petroleum prodn, polymer processing).

Vapor Density

3.2

First Aid Measures

Ingestion

Immediately dilute with 4 to 8 ounces (120 to 240 ml) of milk or water (not to exceed 4 ounces/120 ml in a child). Spontaneous vomiting frequently occurs following ingestion. If spontaneous vomiting does not occur then significant ingestion is unlikely. Administration of activated charcoal is unnecessary. Observe patients with ingestion carefully for the possible development of esophageal or gastrointestinal tract irritation or burns. If signs or symptoms of esophageal irritation or burns are present, consider endoscopy to determine the extent of injury. Patient should be evaluated for burns to the mouth and esophagus following ingestion of low phosphate detergents which are generally more alkaline.

Ingestion

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Occupational asthma has been reported. Aspiration may result in upper airway edema and significant respiratory distress. Difficulty in breathing has been described in animals inhaling high concentrations of anionic surfactants.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Inhalation

Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.

Skin

Skin irritation has been reported after prolonged occupational dermal contact. Skin dryness, irritation, and contact dermatitis have been reported following varying degrees of exposure to detergents.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Destroy contaminated shoes.

Skin

Remove contaminated clothing, wash exposed area with copious amounts of water. A physician should examine the area if irritation or pain persists.

Eyes

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Eyes

Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Handling and Storage

Storage

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.

Storage

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Minimize dust generation and accumulation. Do not get on skin or in eyes. Do not ingest or inhale.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Ingestion

Nausea, vomiting, and diarrhea are common. Oral, pharyngeal and esophageal burns may occur following ingestion of low phosphate detergents which are generally more alkaline. Colitis, esophageal stricture, and irritation of mucous membranes have also been reported.

Inhalation

May cause allergic respiratory reaction. May cause dyspnea (difficult breathing from shortness of breath). May cause headache. May cause nausea and possible vomiting. Causes severe respiratory tract irritation with possible burns.

Skin

Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.

Eyes

Causes eye burns.

Ingestion

May cause liver damage. May cause damage to pancreas. May cause heart damage. May cause paralysis of the extremities. Causes digestive tract irritation with possible burns.

Hazards

Contact with metals may evolve flammable hydrogen gas.

EC Risk Phrase

R 25 43 62

EC Safety Phrase

S 22 36/37 45

UN (DOT)

2811

Exposure Controls/Personal Protection

Personal Protection

Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Respirators

Use NIOSH/MSHA approved respirator appropriate for exposure of concern.

Exposure Effects

Reproductive effects have been reported in animals.

Poison Class

3

Fire Fighting Measures

Flash Point

109

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.

Fire Potential

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures

Small spills/leaks

Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Small spills/leaks

Evacuate area and ventilate. Wear protective equipment. If required, use an inert absrobent. Sweep up and place in an appropriate container for disposal. Wash contaminated surfaces.

Stability and Reactivity

Stability

No data.

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents

Incompatibilities

Strong oxidizing agents.

Disposal Code

9

Decomposition

Chlorine, nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2811

Hazard Class

6.1

Packing Group

I; II; III

HS Code

2924 19 00