Product Identification

Product Name

Cupric acetylacetonate

Synonyms

bis(2,4-Pentanedionato)copper
bis(Acetylacetonato)copper
bis(Acetylacetone)copper
CD 9
Copper acetylacetonate
Copper bis(acetylacetonate)

CAS

13395-16-9

Formula

C10H14CuO4

Molecular Weight

261.77

EINECS

236-477-9

RTECS

GL6520000

RTECS Class

Other

Beilstein/Gmelin

4157957

Beilstein Reference

4-01-00-03662

EC Class

irritant

Physical and Chemical Properties

Appearance

Blue - gray powder.

Solubility in water

0.2 g/L

Melting Point

279 - 283

Vapor Pressure

0.98 (163 C)

Usage

Fungicide.

First Aid Measures

Ingestion

Get medical aid. Wash mouth out with water.

Inhalation

Remove from exposure to fresh air immediately. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container.

Handling

Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.

Hazards Identification

Inhalation

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.

Skin

Causes skin irritation.

Eyes

Causes eye irritation.

Ingestion

Harmful if swallowed. The toxicological properties of this substance have not been fully investigated. May cause central nervous system effects.

EC Risk Phrase

R 20/22

EC Safety Phrase

S 22 36/37

UN (DOT)

3282

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

Increased temperature may be noted in some cases. Abnormally low blood pressure may occur. Mental status may be depressed.

Exposure limit(s)

OSHA: PEL (8 h TWA): 1 mg/m3.

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container.

Stability and Reactivity

Disposal Code

15

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents.

Decomposition

Carbon monoxide, carbon dioxide, 2,4-pentanedione.

Transport Information

UN Number

3282

HS Code

2942 00 00