Product Identification

Product Name

Rhodium chloride trihydrate

Synonyms

Rhodium chloride, trihydrate
Rhodium(III) chloride, trihydrate
Triaquatrichlororhodium

CAS

13569-65-8

Formula

Cl3H6O3Rh

Molecular Weight

263.31

EINECS

233-165-4

RTECS

VI9290000

RTECS Class

Mutagen

Beilstein/Gmelin

11407 (G)

EC Class

harmful, irritant

Physical and Chemical Properties

Appearance

Red deliquescent powder.

Solubility in water

Soluble

Melting Point

475

Boiling Point

800

Density

> 1 g/cm3

Usage

Catalyst,.

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container.

Handling

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

Ingestion of large amounts may cause gastrointestinal irritation.

Inhalation

May cause respiratory tract irritation.

Skin

May cause skin irritation.

Eyes

May cause eye irritation.

EC Risk Phrase

R 22 41

EC Safety Phrase

S 26 39

UN (DOT)

3260

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure limit(s)

TLV: ppm; 0.01 mg/m3 (as TWA) (ACGIH 1995-1996).

Poison Class

3 (Strong toxins)

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Stability and Reactivity

Disposal Code

27

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents.

Decomposition

No data available.

Transport Information

UN Number

3260

HS Code

2843 90 90