Product Identification

Product Name

(S)-(-)-sec-Butylcarbinol

Synonyms

(S)-(-)-2-Methylbutanol
D-(-)-2-Methyl-1-butanol

CAS

1565-80-6

Formula

C5H12O

Molecular Weight

88.14

EINECS

216-366-1

Merck

12,6109

Beilstein/Gmelin

1718809

Beilstein Reference

4-01-00-01666

Physical and Chemical Properties

Appearance

Clear, colorless liquid.

Solubility in water

Soluble

Melting Point

-70

Boiling Point

128

Density

0.8279 g/cm3

Refractive Index

1.4085 (20 C)

First Aid Measures

Ingestion

Get medical aid immediately. Wash mouth out with water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.

Handling and Storage

Storage

Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.

Handling

Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Take precautionary measures against static discharges.

Hazards Identification

Ingestion

May be harmful if swallowed.

Inhalation

Harmful if inhaled.

Skin

May cause skin irritation.

Eyes

May cause eye irritation.

Hazards

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.

EC Risk Phrase

R 10 20

EC Safety Phrase

S 24/25

UN (DOT)

1105

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

43

Autoignition

400

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.

Fire Potential

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.

Stability and Reactivity

Stability

No data.

Incompatibilities

Strong oxidizing agents.

Decomposition

Carbon monoxide, carbon dioxide.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

1105

Hazard Class

3

Packing Group

II; III