Product Identification

Product Name

4'-Methylpropiophenone

Synonyms

1-(4-Methylphenyl)-1-propanone
1-(4-Methylphenyl)propan-1-one
1-(4-Tolyl)-1-propanone
Ethyl 4-methylphenyl ketone
Ethyl p-tolyl ketone
p-Methylpropiophenone

CAS

5337-93-9

Formula

C10H12O

Molecular Weight

148.19999999999999

EINECS

226-267-5

Beilstein/Gmelin

2042137

Beilstein Reference

4-07-00-00722

Physical and Chemical Properties

Appearance

Light yellow liquid.

Solubility in water

Insoluble

Melting Point

91

Boiling Point

238

Vapor Pressure

0.04 (25 C)

Density

1.0053 g/cm3 (0 C)

Partition Coefficient

2.66

Heat Of Vaporization

47.5 kJ/mol

Refractive Index

1.5272 (20 C)

First Aid Measures

Ingestion

Get medical aid. Wash mouth out with water.

Inhalation

Remove from exposure to fresh air immediately.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container.

Handling

Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.

Hazards Identification

Ingestion

May cause irritation of the digestive tract. May be harmful if swallowed.

Inhalation

May cause respiratory tract irritation. May be harmful if inhaled.

Skin

May cause skin irritation. May be harmful if absorbed through the skin.

Eyes

May cause eye irritation.

EC Safety Phrase

S 24/25

Exposure Controls/Personal Protection

Personal Protection

Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

96

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.

Stability and Reactivity

Stability

No data.

Incompatibilities

Strong oxidizing agents.

Decomposition

Carbon monoxide, carbon dioxide.