Product Identification

Product Name

4-Nitrobenzaldehyde

Synonyms

4-Formylnitrobenzene
p-Formylnitrobenzene
p-Nitrobenzaldehyde

CAS

555-16-8

Formula

C7H5NO3

Molecular Weight

151.12

EINECS

209-084-5

RTECS

CU7350000

RTECS Class

Mutagen

Merck

12,6684

Beilstein/Gmelin

386796

Beilstein Reference

4-07-00-00598

Physical and Chemical Properties

Appearance

Beige or brown solid.

Solubility in water

Slightly soluble

Melting Point

106

Boiling Point

300

Vapor Pressure

0.0012 (25 C)

Density

1.546 g/cm3

Partition Coefficient

1.56

Heat Of Vaporization

54.0 kJ/mol

Heat Of Combustion

-3319 kJ/mol

Vapor Density

5.21

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

May cause digestive tract disturbances.

Inhalation

Causes respiratory tract irritation.

Skin

Causes skin irritation.

Eyes

May cause eye irritation and possible burns.

EC Risk Phrase

R 36/37/38

EC Safety Phrase

S 26 36

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Poison Class

3 (Strong toxins)

Fire Fighting Measures

Flash Point

155

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam.

Accidental Release Measures

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code

3

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong bases.

Decomposition

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.

Transport Information

HS Code

2913 00 00