Product Identification

Product Name

Dichlorobis(triphenylphosphine)nickel(II)

Synonyms

Nickel, dichlorobis(triphenylphosphine)
Phosphine, tributyl-, compound with nickel chloride (2:1)

CAS

14264-16-5

Formula

C36H30Cl2NiP2

Molecular Weight

654.20000000000005

EINECS

238-154-8

RTECS

QR6170000

RTECS Class

Other

Beilstein/Gmelin

NA

Physical and Chemical Properties

Appearance

Dark gray solid.

Solubility in water

Insoluble

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid.

Inhalation

Remove from exposure to fresh air immediately. Get medical aid if cough or other symptoms appear.

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket.

Handling

Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.

Hazards Identification

Ingestion

No information found.

Inhalation

May cause respiratory tract irritation.

Skin

May cause skin irritation.

Eyes

May cause eye irritation.

EC Risk Phrase

R 45 34

EC Safety Phrase

S 53 45

UN (DOT)

3282

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron.

Respirators

A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container.

Stability and Reactivity

Disposal Code

15

Stability

No data.

Incompatibilities

Strong oxidizing agents, moisture.

Decomposition

Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide.

Transport Information

UN Number

3282

HS Code

2931 00 95