ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organonickel > Bis(triphenylphosphine)nickel(II)chloride
Bis(triphenylphosphine)nickel(II)chloride
Bis(triphenylphosphine)nickel(II)chloride Basic information
- Product Name:
- Bis(triphenylphosphine)nickel(II)chloride
- Synonyms:
-
- Dichlorobis(triphenyIphosphine)-nickel
- tributyl-phosphin compd. with nickelchloride
- Nickel(II) chloride bis(triphenylphosphine)
- Bis(triphenylphosphine)nick
- Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride
- Phosphine, tributyl-, compound with nickel chloride (2:1)
- Dichlorobis(triphenylphosphine)nickel(Ⅱ)
- Dichlorobis(triphenylphosphine)nickel(II), 98+%
- CAS:
- 14264-16-5
- MF:
- C36H30Cl2NiP2
- MW:
- 654.17
- EINECS:
- 238-154-8
- Product Categories:
-
- Metal Compounds
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- Metal Complexes
- Ni (Nickel) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- metal-phosphine complexes
- Aromatics
- Phosphorylating and Phosphitylating Agents
- Pyridines
- Ni
- Mol File:
- 14264-16-5.mol
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Bis(triphenylphosphine)nickel(II)chloride Chemical Properties
- Melting point:
- 250 °C (dec.)(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- form
- Crystals or Powder
- color
- Dark green to dark gray
- Water Solubility
- insoluble
- Sensitive
- Hygroscopic
- Exposure limits
- NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
- CAS DataBase Reference
- 14264-16-5(CAS DataBase Reference)
- NIST Chemistry Reference
- dichlorobis(triphenylphosphine)nickel(14264-16-5)
- EPA Substance Registry System
- Nickel, dichlorobis(triphenylphosphine)- (14264-16-5)
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Safety Information
- Hazard Codes
- T
- Risk Statements
- 45-43-52/53-34-20/21/22
- Safety Statements
- 53-36/37-45-60-36/37/39-26
- RIDADR
- 3260
- WGK Germany
- 3
- RTECS
- QR6170000
- F
- 21
- TSCA
- Yes
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29310095
MSDS
- Language:English Provider:Dichlorobis(triphenylphosphine)nickel(II)
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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Bis(triphenylphosphine)nickel(II)chloride Usage And Synthesis
Reaction
- Catalyst for hydrosilylation of styrene with diphenysilane
- Catalyst for carboxylation of various aryl chlorides and other derivatives
- Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
- Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
- Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
Chemical Properties
dark green to dark grey crystals or powder
Uses
Coordination compund.
Uses
suzuki reaction
Uses
Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.
Purification Methods
Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]
Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials
Preparation Products
Raw materials
Bis(triphenylphosphine)nickel(II)chlorideSupplier
Zhengzhou Changkuan Technology Co., Ltd Gold
- Tel
- 0371-63769919 18530983798
- sales5@changkuantech.com
Wuhan Huahan Dingcheng New Material Technology Co., Ltd Gold
- Tel
- +86-027-81388558 18963961905
- huahandingcheng@sina.com
Panjin Greenchem Technology Co., Ltd. Gold
- Tel
- 13121959385 13121959385
- chemrocking@bjgreenchem.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
- market03@meryer.com
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Bis(triphenylphosphine)nickel(II)chloride(14264-16-5)Related Product Information
- Potassium chloride
- Nickel(II) chloride hexahydrate
- Ammonium chloride
- Calcium chloride
- Triphenylphosphine
- Bis(triphenylphosphine)palladium(II) chloride
- Polyvinyl chloride
- Nickel oxide
- Tris(triphenylphosphine)rhodiu
- Choline chloride
- Nickel chloride
- Sodium chloride
- Thionyl chloride
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- BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
- Bis-(triphenylphosphino)-cuprous borohydride
- BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE
- Bis(tricyclohexylphosphine)nickel(II) chloride, 99%