Basic information Reaction Safety Supplier Related

Bis(tricyclohexylphosphine)nickel(II) chloride, 99%

Basic information Reaction Safety Supplier Related

Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Basic information

Product Name:
Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
Synonyms:
  • Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
  • Dichlorobis(tricyclohexylphosphine)nickel(II)
  • Bis(tricyclohexylphosphine)nickel(II) Dichloride
  • Bis(tricyclohexylphosphine)nickel(II)chloride,99%
  • Bis(tricyclohexylphosphine)nickel(II) chloride,98% (PCy3)2NiCl2
  • Bis(tricyclohexylphosphine)dichloronickel
  • Dichlorobis(tricyclohexylphosphine)nickel
  • Bis(tricyclohexylphosphine)nickel(II) chloride,98%
CAS:
19999-87-2
MF:
2C18H33P.Cl2Ni
MW:
690.464
Product Categories:
  • Ni
  • metal-phosphine complexes
Mol File:
19999-87-2.mol
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Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Chemical Properties

Melting point:
227-231℃ (DEC.)
storage temp. 
Inert atmosphere,Room Temperature
form 
powder to crystal
color 
Yellow to Amber to Dark red
CAS DataBase Reference
19999-87-2
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-40-43
Safety Statements 
53-36/37-45-60
WGK Germany 
3
HS Code 
2931.90.9051
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Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Usage And Synthesis

Reaction

  1. An approach to five-membered lactams from aliphatic amides and terminal acetylenes by nickel catalysis.
  2. Synthesis of biaryls through nickel-catalyzed Suzuki-Miyaura coupling of amides by carbon-nitrogen bond cleavage.
  3. Ni-catalyzed borylation of aryl fluorides via C-F cleavage.
  4. Nickeland palladium–catalyzed coupling of aryl fluorosulfonates with aryl boronic acids enabled by sulfuryl fluoride.
  5. Nickel-catalyzed one-pot synthesis of biaryls from phenols and arylboronic acids via C-O activation using TCT reagents.

Uses

Catalyst for:

  • Dehydrobrominative polycondensation
  • Arylation reactions
  • Cross-coupling
  • Suzuki-miyaura cross-coupling reactions
  • Kumada coupling of diaryl sulfates with Grignard reagents
  • Olefin dimerization

Bis(tricyclohexylphosphine)nickel(II) chloride, 99%Supplier

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