ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic rhodium > (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Basic information
- Product Name:
- (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
- Synonyms:
-
- NORBORNADIENE RHODIUM(1) CHLORIDE
- NORBORNADIENE RHODIUM(I) CHLORIDE DIMER
- RHODIUM(I) CHLORIDE 2,5-NORBORNADIENE COMPLEX DIMER
- Chloronorbornadienerhodium(I)dimer,99%
- di-ae-chlorobis(norbornadiene) dirhodium(i)
- bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]di-mu-chlorodirhodium
- BICYCLO(2.2.1)HEPTA-2,5-DIENE-RHODIUM(I)
- Chloro(norbornadiene)rhodium(I), dimer, 99.9%
- CAS:
- 12257-42-0
- MF:
- C14H16Cl2Rh28*
- MW:
- 460.99
- EINECS:
- 235-510-4
- Product Categories:
-
- organometallic complexes
- Rh
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- Metal Complexes
- Rh (Rhodium) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Mol File:
- 12257-42-0.mol
More
Less
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Chemical Properties
- Melting point:
- 239-241°C (dec.)
- storage temp.
- 2-8°C
- form
- Powder
- color
- yellow to orange
- Water Solubility
- Slightly soluble in acetone, chloroform, methanol and insoluble in water.
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
More
Less
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
More
Less
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Usage And Synthesis
Chemical Properties
mustard yellow crystals
Uses
Di-μ-chlorobis(norbornadiene)dirhodium(I) is used as catalysts in olefin hydroformylation, olefin hydrogenation and olefin isomerization
Purification Methods
It recrystallises from hot CHCl3/pet ether as fine crystals soluble in CHCl3 and *C6H6 but is almost insoluble in Et2O or pet ether. [Abel et al. J Chem Soc 3178 1959.]
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMERSupplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006608290; 18621169109
- market03@meryer.com
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
BeiJing Hwrk Chemicals Limted
- Tel
- 0757-86329057 18501085097
- sales3.gd@hwrkchemical.com
More
Less
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER(12257-42-0)Related Product Information
- GRUBBS CATALYST 2ND GENERATION
- Ruthenium acetylacetonate
- Benzeneruthenium(II) chloride dimer
- [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
- Tris(triphenylphosphine)ruthenium(II) chloride
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
- Dichloro(p-cymene)ruthenium(II) dimer
- Rhodium(II) acetate dimer
- Ruthenium(II) chloride mesitylene dimer
- Tris(triphenylphosphine)rhodiu
- Rhodium(III) 2,4-pentanedionate
- Bis(tricyclohexylphosphine)nickel(II) chloride, 99%
- Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
- 172222-30-9
- EXO-NORBORNEOL
- 2,5-Norbornadiene
- Rhodium
- (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER