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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organic rhodium >  (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Basic information

Product Name:
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
Synonyms:
  • NORBORNADIENE RHODIUM(1) CHLORIDE
  • NORBORNADIENE RHODIUM(I) CHLORIDE DIMER
  • RHODIUM(I) CHLORIDE 2,5-NORBORNADIENE COMPLEX DIMER
  • Chloronorbornadienerhodium(I)dimer,99%
  • di-ae-chlorobis(norbornadiene) dirhodium(i)
  • bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]di-mu-chlorodirhodium
  • BICYCLO(2.2.1)HEPTA-2,5-DIENE-RHODIUM(I)
  • Chloro(norbornadiene)rhodium(I), dimer, 99.9%
CAS:
12257-42-0
MF:
C14H16Cl2Rh28*
MW:
460.99
EINECS:
235-510-4
Product Categories:
  • organometallic complexes
  • Rh
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Rh (Rhodium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
Mol File:
12257-42-0.mol
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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Chemical Properties

Melting point:
239-241°C (dec.)
storage temp. 
2-8°C
form 
Powder
color 
yellow to orange
Water Solubility 
Slightly soluble in acetone, chloroform, methanol and insoluble in water.
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
10-21
TSCA 
No
HS Code 
28439000

MSDS

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Usage And Synthesis

Chemical Properties

mustard yellow crystals

Uses

Di-μ-chlorobis(norbornadiene)dirhodium(I) is used as catalysts in olefin hydroformylation, olefin hydrogenation and olefin isomerization

Purification Methods

It recrystallises from hot CHCl3/pet ether as fine crystals soluble in CHCl3 and *C6H6 but is almost insoluble in Et2O or pet ether. [Abel et al. J Chem Soc 3178 1959.]

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMERSupplier

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