Rhodium(III) 2,4-pentanedionate
Rhodium(III) 2,4-pentanedionate Basic information
- Product Name:
- Rhodium(III) 2,4-pentanedionate
- Synonyms:
-
- 4-pentanedionato-o,o’)-tris((oc-6-11)-rhodiu
- Rhodium acetylacetonate
- Rhodium tris(acetylacetonate)
- Rhodium, tris(2,4-pentanedionato)-
- Rhodium, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-
- Tris(2,4-pentanedionato)rhodium
- Tris(acetylacetonato)rhodium
- RhodiuM(III) acetylacetonate,98% Rh(CH3COCHCOCH3)3
- CAS:
- 14284-92-5
- MF:
- C15H21O6Rh
- MW:
- 400.23
- EINECS:
- 238-192-5
- Product Categories:
-
- Rh
- metal beta-diketonate complexes
- Mol File:
- 14284-92-5.mol
Rhodium(III) 2,4-pentanedionate Chemical Properties
- Melting point:
- 263-264 °C(lit.)
- Boiling point:
- >280°C
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Powder
- color
- Yellow to yellow-orange
- Specific Gravity
- 1.607
- Water Solubility
- insoluble
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 - CAS DataBase Reference
- 14284-92-5
- NIST Chemistry Reference
- Rhodium, tris(2,4-pentanedionato-o,o')-(14284-92-5)
- EPA Substance Registry System
- Rhodium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14284-92-5)
Safety Information
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-36/37/38-40-63
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- TSCA
- Yes
- HS Code
- 28439000
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
Rhodium(III) 2,4-pentanedionate Usage And Synthesis
Chemical Properties
Yellow/Orange Crystals
Uses
Rhodium(III) 2,4-pentanedionate is used in catalytic reagents for organic synthesis. Rhodium(III) 2,4-pentanedionate is useful for hydrosilylation of a variety of organic substrates like alkenes, terminal or internal acetylenes, conjugated dienes, alpha, beta -unsaturated aldehydes and allylic compounds. It performs the role of a catalyst in well-known reactions such as transformation processes including hydrogenation, ethanol steam reforming, CO oxidation, and NOx reduction. Rhodium acetylacetonate, as the organic solvent-soluble source of rhodium metal ions, can be used to prepare monodisperse size/shape controlled Rh nanocrystals. Rh nanocrystal monolayers have been reported to show high activity for hydrogenation of vinylcyclohexene to selectively produce ethylcyclohexene. The size/shape controlled nanocrystals find a variety of applications in oil refining processes, chemical synthesis and fuel cell technology.
Uses
Very effective catalyst for the hydrogenation of carboxylic acids when combined with group 6 or group 7 metal carbonyls.
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Rhodium(III) 2,4-pentanedionate(14284-92-5)Related Product Information
- Bis(acetylacetonato)cobalt
- Ferric acetylacetonate
- Nickel(II) acetylacetonate
- LANTHANUM ACETYLACETONATE HYDRATE
- GALLIUM(III) 2,4-PENTANEDIONATE
- Dicarbonylacetylacetonato rhodium(I)
- Aluminum acetylacetonate
- LITHIUM ACETYLACETONATE
- Magnesium acetylacetonate dihydrate
- BERYLLIUM 2,4-PENTANEDIONATE
- LEAD(II) ACETYLACETONATE
- Manganic acetylacetonate
- Chromium(III) acetylacetonate
- HAFNIUM(IV) 2,4-PENTANEDIONATE
- Cobaltic acetylacetonate
- CADMIUM 2,4-PENTANEDIONATE, HYDRATE
- MANGANESE(II) ACETYLACETONATE
- NICKEL(II) ACETYLACETONATE HYDRATE