ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic ruthenium > Ruthenium acetylacetonate
Ruthenium acetylacetonate
Ruthenium acetylacetonate Basic information
- Product Name:
- Ruthenium acetylacetonate
- Synonyms:
-
- RUTHENIUM(III) 2,4-PENTANEDIONATE
- RUTHENIUM(III) ACETYLACETONATE
- TRIS(ACETYLACETONATO)RUTHENIUM(III)
- TRIS(PENTANE-2,4-DIONATO)RUTHENIUM(III)
- 2,4-PENTANEDIONE, RUTHENIUM(III) DERIVATIVE
- 4-pentanedionato-o,o’)-tris((oc-6-11)-rutheniu
- Ruthenium(III) 2,4-pentanedionate~Tris(acetylacetonato)ruthenium(III)~Tris(2,4-pentanedionato)ruthenium(III)
- Rutheniumacetylacetonateredbrownxtl
- CAS:
- 14284-93-6
- MF:
- C15H21O6Ru
- MW:
- 398.39
- EINECS:
- 238-193-0
- Product Categories:
-
- Ru
- chemical reaction,pharm,electronic,materials
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- metal beta-diketonate complexes
- Metal Complexes
- Ru (Ruthenium) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Mol File:
- 14284-93-6.mol
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Ruthenium acetylacetonate Chemical Properties
- Melting point:
- 260 °C (dec.)(lit.)
- storage temp.
- Store below +30°C.
- form
- Crystalline
- color
- White
- Water Solubility
- Soluble in most organic solvents such as acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene. Insoluble in water.
- InChIKey
- RTZYCRSRNSTRGC-LNTINUHCSA-K
- EPA Substance Registry System
- Ruthenium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14284-93-6)
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Safety Information
- Hazard Codes
- Xi,T
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-24/25
- WGK Germany
- 3
- F
- 10
- TSCA
- Yes
- HS Code
- 28439000
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
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Ruthenium acetylacetonate Usage And Synthesis
Chemical Properties
dark-red crystals
Uses
Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.
Purification Methods
Purify the complex by recrystallisation from *benzene. [Wilkinson J Am Chem Soc 74 6146 1952, Beilstein 1 IV 3677.]
Ruthenium acetylacetonateSupplier
Nanjing Pharmaluxury Co., Ltd. Gold
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- 025-83726959 15851816062
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Chenzhou Gaoxin Platinum Industry Co., Ltd. Gold
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Shaanxi Rock New Materials Co., Ltd. Gold
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- 0917-8888777, 3380777,18691786767; 15619786767
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Panjin Greenchem Technology Co., Ltd. Gold
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- 13121959385 13121959385
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J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
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Ruthenium acetylacetonate(14284-93-6)Related Product Information
- Ruthenium
- Ethyl 2,4-dioxovalerate
- Tricine
- BIS-Tris
- Bis(acetylacetonato)cobalt
- Ferric acetylacetonate
- Cupric acetylacetonate
- Tris(hydroxymethyl)aminomethane
- Pentane
- Zinc(II) acetylacetonate
- Aluminum acetylacetonate
- BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE)
- Acetylacetone
- Bis(2,4-pentanedionato-O,O')palladium(II)
- VANADIUM(III) ACETYLACETONATE
- Nickel(II) acetylacetonate
- Chromium(III) acetylacetonate
- Molybdenyl acetylacetonate