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Ruthenium acetylacetonate

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Ruthenium acetylacetonate Basic information

Product Name:
Ruthenium acetylacetonate
Synonyms:
  • RUTHENIUM(III) 2,4-PENTANEDIONATE
  • RUTHENIUM(III) ACETYLACETONATE
  • TRIS(ACETYLACETONATO)RUTHENIUM(III)
  • TRIS(PENTANE-2,4-DIONATO)RUTHENIUM(III)
  • 2,4-PENTANEDIONE, RUTHENIUM(III) DERIVATIVE
  • 4-pentanedionato-o,o’)-tris((oc-6-11)-rutheniu
  • Ruthenium(III) 2,4-pentanedionate~Tris(acetylacetonato)ruthenium(III)~Tris(2,4-pentanedionato)ruthenium(III)
  • Rutheniumacetylacetonateredbrownxtl
CAS:
14284-93-6
MF:
C15H21O6Ru
MW:
398.39
EINECS:
238-193-0
Product Categories:
  • Ru
  • chemical reaction,pharm,electronic,materials
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • metal beta-diketonate complexes
  • Metal Complexes
  • Ru (Ruthenium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
Mol File:
14284-93-6.mol
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Ruthenium acetylacetonate Chemical Properties

Melting point:
260 °C (dec.)(lit.)
storage temp. 
Store below +30°C.
form 
Crystalline
color 
White
Water Solubility 
Soluble in most organic solvents such as acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene. Insoluble in water.
InChIKey
RTZYCRSRNSTRGC-LNTINUHCSA-K
EPA Substance Registry System
Ruthenium, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14284-93-6)
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Safety Information

Hazard Codes 
Xi,T
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
WGK Germany 
3
10
TSCA 
Yes
HS Code 
28439000

MSDS

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Ruthenium acetylacetonate Usage And Synthesis

Chemical Properties

dark-red crystals

Uses

Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.

Purification Methods

Purify the complex by recrystallisation from *benzene. [Wilkinson J Am Chem Soc 74 6146 1952, Beilstein 1 IV 3677.]

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