ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organonickel > [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Basic information
- Product Name:
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
- Synonyms:
-
- Ni(dppf)Cl2
- DPPF·NICL2
- 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE NICKEL DICHLORIDE
- [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II) DICHLORIDE
- DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]NICKEL(II)
- (1,1'-bis(diphenylphosphino)ferrocene)-dichloroni
- [1, 1’-Bis(diphenyphosphino)ferrocene]dichloronickel(II)
- Dichlorobisdiphenylphosphinoferrocenenickel
- CAS:
- 67292-34-6
- MF:
- C34H22Cl2FeNiP2
- MW:
- 677.94
- Product Categories:
-
- Ni
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Fe (Iron) Compounds
- Ferrocenes
- Homogeneous Catalysts
- Metal Complexes
- Metallocenes
- Ni (Nickel) Compounds
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- pharmacetical
- Metal Compounds
- Mol File:
- 67292-34-6.mol
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Chemical Properties
- Melting point:
- 285 °C (dec.)(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- crystal
- color
- green micro
- Water Solubility
- Insoluble in water.
- Exposure limits
- NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
- InChI
- InChI=1S/2C17H11P.2ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-6,9-12,18H;2*1H;;/q;;;;+2;/p-2
- InChIKey
- YLRDSVJNPNAGLK-UHFFFAOYSA-L
- SMILES
- [Cl-][Ni+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-]
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Safety Information
- Hazard Codes
- T
- Risk Statements
- 45-42/43
- Safety Statements
- 53-22-36/37/39-45
- RIDADR
- 2811
- WGK Germany
- 3
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Usage And Synthesis
Chemical Properties
Yellow powder
Uses
diphosphine 1,1'-bis(diphenylphosphino)ferrocene (dppf) are used in transition metal-catalyzed reactions to synthesize pharmaceuticals and agrochemicals.
Uses
(1,1''-Bis(diphenylphosphino)ferrocene)dichloronickel(II) is an organometallic catalyst used in a variety of synthetic applications, such as the gem-?difluoropropargylation of alkylzinc reagents, or cross coupling reactions to form 2,?3,?5,?6-?tetrasubstituted dehydropiperidines.
Uses
suzuki reaction
reaction suitability
core: nickel
reagent type: catalyst
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Preparation Products And Raw materials
Raw materials
[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)Supplier
Panjin Greenchem Technology Co., Ltd. Gold
- Tel
- 13121959385
- chemrocking@bjgreenchem.com
J & K SCIENTIFIC LTD.
- Tel
- 18210857532; 18210857532
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006356688 18621169109
- market03@meryer.com
INTATRADE GmbH
- Tel
- +49 3493/605464
- sales@intatrade.de
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
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[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)(67292-34-6)Related Product Information
- Ferrocene
- Chlorodiphenylphosphine
- Diphenylphosphine
- N-(Carboxymethyl)-N-(phosphonomethyl)-glycine
- 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
- 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride
- Nickle chloride
- Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium
- [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- Silane,[1,1'-biphenyl]-3-yltrimethyl-
- 1,1'-Bis(diphenylphosphino)ferrocene
- DICHLOROBIS(TRIMETHYLPHOSPHINE)NICKEL(II)
- NICKELOCENE
- Nickel Iron (80:20wt%) in cone shaped (refer to drawing)
- Nickel chloride
- ALLYL(CYCLOPENTADIENYL)NICKEL(II) 97
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)