1,1'-Bis(diphenylphosphino)ferrocene
1,1'-Bis(diphenylphosphino)ferrocene Basic information
- Product Name:
- 1,1'-Bis(diphenylphosphino)ferrocene
- Synonyms:
-
- DPPF
- 1,1''-BIS(DIPHENYLPHOSPHINO)ERROCENE
- 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE (DPPF)
- DPPF/1,1''-BIS(DIPHENYLPHOSPHINO) FERROCENE
- 1,1'-Bis(diphenylphosphiNA)ferrocene
- DPPF, (Ferrocene-1,1'-diyl)bis(diphenylphosphine)
- 1,1-(twophenylphosphine)Er Maotie
- 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE
- CAS:
- 12150-46-8
- MF:
- C34H28FeP210*
- MW:
- 554.38
- EINECS:
- 640-119-0
- Product Categories:
-
- Miscellaneous
- pharmacetical
- Ligand
- Catalysts-Ligands
- Classes of Metal Compounds
- Fe (Iron) Compounds
- Boron, Nitrile, Thio,& TM-Cpds
- Ferrocenes
- Metallocenes
- Phosphine Ligands
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Aromatics
- Catalyst
- Phosphines
- Chelating Agents & Ligands
- Pharmaceutical intermediates
- Achiral Phosphine
- Aryl Phosphine
- Mol File:
- 12150-46-8.mol
1,1'-Bis(diphenylphosphino)ferrocene Chemical Properties
- Melting point:
- 181-182 °C (dec.)(lit.)
- storage temp.
- 2-8°C
- solubility
- Chloroform, Ethyl Acetate
- form
- crystal
- color
- yellow to orange
- Water Solubility
- Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
- Sensitive
- Air Sensitive
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Stability:
- Stable. Incompatible with strong oxidizing agents.
- CAS DataBase Reference
- 12150-46-8(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,1'-Bis(diphenylphosphino)ferrocene(12150-46-8)
Safety Information
- Hazard Codes
- T,Xi,Xn
- Risk Statements
- 25-36/37/38-20/21/22
- Safety Statements
- 22-24/25-45-28A-36-26-36/37/39
- RIDADR
- 3467
- WGK Germany
- 3
- F
- 10-23
- TSCA
- No
- HazardClass
- IRRITANT
- HS Code
- 29319090
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
1,1'-Bis(diphenylphosphino)ferrocene Usage And Synthesis
Reaction
- Ligand for Pd-catalyzed cross-coupling.
- Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.
- Ligand for Ni-catalyzed amination of aryl chlorides.
- Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles.
- Ligand for Ni-catalyzed Suzuki reactions.
- Ni-catalyzed hydroamination of 1,3-dienes.
- Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.
- Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.
- Ligand for Ru-catalyzed reduction of nitriles to primary amines.
- Ligand for Rh-catalyzed alkyne head-to-tail dimerization.
- Ligand for Rh-catalyzed cross-coupling
- Ligand for Rh-catalyzed olefin isomerization
- Ligand for Ni or Rh-catalyzed borylation
- Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.
Chemical Properties
1,1'-Bis(diphenylphosphino)ferrocene is deep yellow crystalline powder
Uses
1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.
Uses
1,1'-Bis(diphenylphosphino)ferrocene used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which i s a popular reagent for palladium-catalyzed coupling reactions.
General Description
Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.
Purification Methods
Wash it with distilled H2O and dry it in a vacuum. Dissolve it in ca 5 parts of hot dioxane and cool to give orange crystals m 181-183o. Recrystallisation from *C6H6/heptane (1:2) gives a product with m 183-184o. [Bishop et al. J Organomet Chem 27 241 1971.]
1,1'-Bis(diphenylphosphino)ferrocene Preparation Products And Raw materials
Preparation Products
Raw materials
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1,1'-Bis(diphenylphosphino)ferrocene(12150-46-8)Related Product Information
- Ferrocene
- Diphenylphosphine oxide
- Diphenylphosphine
- Chlorodiphenylphosphine
- N-(Carboxymethyl)-N-(phosphonomethyl)-glycine
- 1,3-Bis(diphenylphosphino)propane
- 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
- 1,2-Bis(diphenylphosphino)ethane
- (1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)TETRACARBONYLCHROMIUM
- (S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
- (R)-CTH-JAFAPHOS
- Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
- [1,1'-Bis(diphenylphosphino)ferrocene]dichlorocobalt(II)
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE
- 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex