[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties

Melting point:

275-280 °C(lit.)

storage temp. 

Keep in dark place,Inert atmosphere,Room temperature

solubility 

Soluble in dichloromethane.

form 

powder

color 

red to very dark red

Stability:

Hygroscopic

Safety Information

Hazard Codes 

Xn,Xi

Risk Statements 

20/21/22-36/37/38-40

Safety Statements 

23-24/25-26-36/37

WGK Germany 

3

TSCA 

No

HazardClass 

IRRITANT

HS Code 

28439000

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Usage And Synthesis

Uses

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds.Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.

Chemical Properties

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid

Uses

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.

Uses

suzuki reaction

Uses

Catalyst for C-C and C-N coupling reaction.

Application

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

Mechanism of action

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.

R = usually sp2 hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)Related Product Information

• Diphenylphosphine oxide
• Dicyclohexylchlorophosphine
• Chlorodiphenylphosphine
• ETHYNYLFERROCENE
• Tricyclohexyl phosphine
• Acetylferrocene
• Ferrocene
• Palladium chloride
• Tetrakis(triphenylphosphine)platinum
• [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
• Dichloro(1,5-cyclooctadien)ruthenium(II) polymer
• 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
• DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II)
• ISOPROPYLDIPHENYLPHOSPHINE
• 1,1'-Bis(diphenylphosphino)ferrocene
• Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct
• Palladium
• 1,3-Cyclopentadiene