Dicyclohexylchlorophosphine
Dicyclohexylchlorophosphine Basic information
- Product Name:
- Dicyclohexylchlorophosphine
- Synonyms:
-
- Chlorodicyclohexylphosphine ,96%
- Chlorodicyclohexylphosphine, 97% 5GR
- 98% (C6H11)2PCl
- chlorodicyclohexylphosphane
- Phosphinous chloride, P,P-dicyclohexyl-
- Chlorodicyclohexylphosphine 97%
- Chlorodicyclohexylphosphine Synonyms Dicyclohexylchlorophosphine
- Dicyclohexylphosphine chloride
- CAS:
- 16523-54-9
- MF:
- C12H22ClP
- MW:
- 232.73
- Product Categories:
-
- organophosphine halide
- Achiral Phosphine
- Catalysis and Inorganic Chemistry
- Phosphorus Compounds
- Alkyl Phosphine
- P-Cl
- Chlorophosphines
- Phosphines
- Phosphorus Precursors
- Mol File:
- 16523-54-9.mol
Dicyclohexylchlorophosphine Chemical Properties
- Melting point:
- 126-128 °C
- Boiling point:
- 165 °C/12 mmHg (lit.)
- Density
- 1.054 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.533(lit.)
- Flash point:
- >230 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Liquid
- Specific Gravity
- 1.054
- color
- Colorless to pale yellow
- Water Solubility
- reacts violently
- Sensitive
- Air & Moisture Sensitive
- InChI
- InChI=1S/C12H22ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
- InChIKey
- AKJFBIZAEPTXIL-UHFFFAOYSA-N
- SMILES
- P(C1CCCCC1)(C1CCCCC1)Cl
- CAS DataBase Reference
- 16523-54-9(CAS DataBase Reference)
Safety Information
- Hazard Codes
- C
- Risk Statements
- 14-34
- Safety Statements
- 26-27-36/37/39-45-8
- RIDADR
- UN 3265 8/PG 2
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29319090
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
Dicyclohexylchlorophosphine Usage And Synthesis
Chemical Properties
clear colorless liquid
Uses
Dicyclohexylchlorophosphine is used as pharmaceutical intermediate. It is also used in the synthesis of various phosphines.
Uses
Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:
- 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
- 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.
Application
Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:
1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis?Arbuzov type rearrangements.
1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.
Precautions
Store in cool, dry conditions in well sealed containers. Protect from humidity and water. Store under dry inert gas. It is sensitive to air and moisture. Incompatible with strong oxidizing agents.
Dicyclohexylchlorophosphine Preparation Products And Raw materials
Preparation Products
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Dicyclohexylchlorophosphine(16523-54-9)Related Product Information
- Trimethylamine hydrochloride
- Tetramethylammonium chloride
- Dicyclohexylcarbodiimide
- Dicyclohexylphenylphosphine
- Tungstic acid
- Tricyclohexyl phosphine
- Tris(triphenylphosphine)rhodiu
- Benzyltriethylammonium chloride
- Benzyltrimethylammonium chloride
- ISOPROPYLMAGNESIUM CHLORIDE
- Didecyl dimethyl ammonium chloride
- DICYCLOHEXYLPHOSPHINYL CHLORIDE
- CYCLOHEXYLPHOSPHINE
- DICYCLOHEXYLPHOSPHINE
- DICHLOROBIS(CHLORODICYCLOHEXYLPHOSPHINE) PALLADIUM (II)
- DI-1-ADAMANTYLPHOSPHINIC CHLORIDE
- DICHLORO(CHLORODICYCLOHEXYLPHOSPHINE) PALLADIUM (II) DIMER
- Dicyclohexylchlorophosphine