X-PHOS Chemical Properties

Melting point:

187-190 °C(lit.)

Boiling point:

569.8±50.0 °C(Predicted)

storage temp. 

Inert atmosphere,Room Temperature

solubility 

Benzene (Slightly)

form 

Powder

color 

white

Sensitive 

Air Sensitive

Stability:

Air Sensitive

InChIKey

UGOMMVLRQDMAQQ-UHFFFAOYSA-N

CAS DataBase Reference

564483-18-7(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xn

Risk Statements 

36/37/38-22-40

Safety Statements 

37/39-26-36/37

WGK Germany 

3

TSCA 

No

HS Code 

29319090

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich

X-PHOS Usage And Synthesis

Reaction

1.  Exceptional ligands for Pd-catalyzed amination and amidation of aryl sulfonates.
2.  Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling reaction and carbonyl enolate coupling.
3.  Ligand used for the chemoselective amination of aryl chlorides.
4.  Ligand used for the Pd-catalyzed borylation of aryl chlorides, for the formation of trifluoroborates.
5.  Ligand used for the Pd-catalyzed amination of vinyl halides and triflates.
6.  Ligand used for the Pd-catalyzed three-component synthesis of indoles.
7.  Ligand used for the Pt-catalyzed regioselective hydrosilylation of functionalized terminal arylalkynes.
8.  Ligand used for the Pd-catalyzed synthesis of carbazoles.
9.  Ligand used for the Pd-catalyzed Suzuki-Miyaura coupling of aryl chloride and NHC-boranes.
10.  Ligand used for the direct arylation of picoline N-oxide.
11.  Ligand used for the Negishi coupling of 2-heterocyclic organozinc reagents.
12.  Catalyst for a phosphine-catalyzed Heine reaction.
13.  Ligand used for the palladium-catalyzed oxidative coupling of indoles and heteroarenes.
14.  Ligand used for the silver-catalyzed hydrogenation of aldehydes.
15.  Ligand used for the palladium-catalyzed cyanation of heterycyclic halides.

X-PHOS(564483-18-7)Related Product Information

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• X-PHOS
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• PNP-PHOS DINA
• CYCLOHEXYLPHOSPHINE
• DICYCLOHEXYLPHOSPHINE
• GOAT F(AB')2 ANTI-HUMAN LAMBDA (F+B) ALK PHOS