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2-(Dicyclohexylphosphino)-2'-methylbiphenyl

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2-(Dicyclohexylphosphino)-2'-methylbiphenyl Basic information

Product Name:
2-(Dicyclohexylphosphino)-2'-methylbiphenyl
Synonyms:
  • MePhos 97%
  • 2-Dicyclohexylphosphino-2'-methyl-)-1,1'-biphenyl
  • 2-(DICYCLOHEXYLPHOSPHINO)-2'-METHYLBIPHENYL
  • dicyclohexyl-[2-(2-methylphenyl)phenyl]phosphane
  • 2-Dicyclohexylphosphino-2'-methylbiphenyl,min.98%MePhos
  • Me-phos
  • 2-Methyl-2μ-dicyclohexylphosphinobiphenyl, MebiphPCy2, MePhos
  • 2-(Dicyclohexylphosphino)-2'-methylbiphenyl,98%
CAS:
251320-86-2
MF:
C25H33P
MW:
364.5
EINECS:
607-557-4
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • Biphenyl & Diphenyl ether
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts
Mol File:
251320-86-2.mol
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2-(Dicyclohexylphosphino)-2'-methylbiphenyl Chemical Properties

Melting point:
107-111 °C
Boiling point:
499.3±24.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Toluene
form 
crystal
color 
white
Water Solubility 
insoluble
Sensitive 
Air Sensitive
InChI
InChI=1S/C25H33P/c1-20-12-8-9-17-23(20)24-18-10-11-19-25(24)26(21-13-4-2-5-14-21)22-15-6-3-7-16-22/h8-12,17-19,21-22H,2-7,13-16H2,1H3
InChIKey
GPVWUKXZFDHGMZ-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)(C1CCCCC1)C1=CC=CC=C1C1=CC=CC=C1C
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29310099

MSDS

  • Language:English Provider:ACROS
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2-(Dicyclohexylphosphino)-2'-methylbiphenyl Usage And Synthesis

Reaction

  1. Ligand used for the Pd-catalyzed formation of a-arylketones.
  2. Ligand used for the Pd-catalyzed amination reaction.
  3. Ligand used for the Pd-catalyzed hydrazone arylation.
  4. Ligand used for the Pd-catalyzed synthesis of 5,5-disubstituted butenolides.
  5. Ligand used for the Pd-catlyzed direct arylation of polyfluorinated arenes at room temperature.

Chemical Properties

White crystals or crystalline powder

Uses

suzuki reaction

Uses

2-(Dicyclohexylphosphino)-2''-methyl-biphenyl (CAS# 251320-86-2) can be used as a catalyst precursor to produce higher alcohols from syngas. It can also be used as a delta-lactone derivatives.

Uses

2-(Dicyclohexylphosphino)-2'-methylbiphenyl is a Ligand used for the Pd-catalyzed formation of a-arylketones

2-(Dicyclohexylphosphino)-2'-methylbiphenylSupplier

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