2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl Chemical Properties

Melting point:

121-124 °C(lit.)

Boiling point:

539.6±43.0 °C(Predicted)

storage temp. 

Keep in dark place,Sealed in dry,Room Temperature

pka

5.04±0.18(Predicted)

form 

crystal

color 

white

Water Solubility 

Insoluble

Sensitive 

Air Sensitive

InChIKey

ZEMZPXWZVTUONV-UHFFFAOYSA-N

CAS DataBase Reference

213697-53-1(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi,Xn

Risk Statements 

36/37/38-22

Safety Statements 

26-36/37/39

WGK Germany 

3

TSCA 

No

HazardClass 

AIR SENSITIVE

HS Code 

29310099

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS

2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl Usage And Synthesis

Reaction

1. Ligand used in the Pd-catalyzed Suzuki coupling and animation of unactivated aryl chlorides. The reactions generally occur at room temperature and give high yields of product.
2. Ligand used in Pd-catalyzed C-N bond formation. A general synthesis of N6-aryl-2'deoxyadenosine analogues.
3. Ligand used in Pd-catalyzed N-arylation of indoles.
4. Ligand used in Pd-catalyzed synthesis of aryl-tert-butyl ethers.
5. Effective ligand in the Pd-catalyzed arylation of ester enolates.
6. Ligand employed in arylation of ketone enolates using ortho-halo nitrobenezenes.
7. Ligand employed in the amination of aryl nonaflates using Pd catalysts.
8. Ligand used for cascade alkenyl amination/Heck reaction for the synthesis of indoles.
9. Ligand used in Pd-catalyzed Kumada-Corriu cross coupling at low temperatures.
10. Ligand used in Rh-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines.
11. Ligand used in Au-catalyzed cycloisomerization of allenes.

2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl(213697-53-1)Related Product Information

• N,N-Dimethylbenzylamine
• Biphenyl
• 1,3-Bis(aminomethyl)benzene
• Dimethylamine
• 2-(Dicyclohexylphosphino)biphenyl
• Dimethylamine hydrochloride
• 3-Dimethylaminopropylamine
• Minocycline
• 2-(Dicyclohexylphosphino)-2'-methylbiphenyl
• 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl
• DICYCLOHEXYLPHOSPHINE
• CYCLOHEXYLPHOSPHINE
• DIBUTYLPHENYLPHOSPHINE
• DI-N-PENTYLPHENYLPHOSPHINE
• Dicyclohexylphenylphosphine
• 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl
• m-xylenediamine