1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Chemical Properties

Melting point:

294-300 °C

storage temp. 

-20°C

form 

Crystalline solid

color 

red-orange microcrystal

InChI

InChI=1S/2C17H26P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*7-8,13-16H,1-6,9-12H2;2*1H;;/q;;;;;+2/p-2

InChIKey

HRAMBTUEZQOQRK-UHFFFAOYSA-L

SMILES

[CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[CH]1[CH][CH][CH][C]1P(C1CCCCC1)C1CCCCC1.[Pd](Cl)Cl.[Fe] |^1:0,1,2,3,4,18,19,20,21,22|

CAS DataBase Reference

917511-90-1

Safety Information

WGK Germany 

3

1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride Usage And Synthesis

Uses

1,1'-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride is an air-stable catalyst useful in the arylation of various ketones with aryl chlorides and aryl bromides.

Uses

1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl₂) can be used as a catalyst in the synthesis of:

• α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.
• Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH₂ group and arylboronic acids.
• α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride(917511-90-1)Related Product Information

• [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
• 1,1 bis(di-isopropylphosphine)ferrocene palladium dichloride
• dibromo[1,1'-bis(diphenylphosphino)ferrocene]palladium(II)
• [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride
• [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
• [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)
• Silane,[1,1'-biphenyl]-3-yltrimethyl-
• 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,