Product Identification

Product Name

2-Fluorotoluene

Synonyms

1-Fluoro-2-methylbenzene
o-Fluorotoluene

CAS

95-52-3

Formula

C7H7F

Molecular Weight

110.13

EINECS

202-428-5

RTECS

XT2579000

RTECS Class

Other

Merck

13,4207

Beilstein/Gmelin

1853362

Beilstein Reference

4-05-00-00799

EC Class

highly flammable

Physical and Chemical Properties

Appearance

A colorless liquid with an aromatic odor.

Solubility in water

Insoluble

Melting Point

-62

Boiling Point

113

Vapor Pressure

47

Density

1.0041 g/cm3 (13 C)

Partition Coefficient

2.68

Vapor Density

3.8

Refractive Index

1.4671 (17.3 C)

First Aid Measures

Ingestion

Get medical aid. Wash mouth out with water.

Inhalation

Remove from exposure to fresh air immediately. Get medical aid if cough or other symptoms appear.

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.

Handling

Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.

Hazards Identification

Inhalation

Harmful if inhaled. Causes respiratory tract irritation.

Skin

Causes skin irritation.

Eyes

Causes eye irritation.

Ingestion

Causes gastrointestinal irritation with nausea, vomiting and diarrhea.

Hazards

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.

EC Risk Phrase

R 11 36/37/38

EC Safety Phrase

S 16 23 36

UN (DOT)

2388

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

The toxological properties of this substance have not been fully investigated.

Poison Class

2

Fire Fighting Measures

Flash Point

12

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Containers may explode in the heat of a fire. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Fire Potential

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.

Stability and Reactivity

Disposal Code

2

Stability

No data.

Incompatibilities

Strong oxidizing agents.

Decomposition

Carbon monoxide, carbon dioxide, hydrogen fluoride.

Combustion Products

May contain toxic fluoride fumes.

Transport Information

UN Number

2388

Hazard Class

3

Packing Group

II

HS Code

2903 69 90