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2-Fluorotoluene

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2-Fluorotoluene Basic information

Product Name:
2-Fluorotoluene
Synonyms:
  • 1-Fluor-2-methylbenzol
  • 1-fluoro-2-methyl-benzen
  • 1-Fluoro-2-methylbenzene
  • 1-fluoro-2-methyl-benzene
  • 1-Methyl-2-fluorobenzene
  • 2-fluoromethylbenzene
  • 2-FLUOROTOLUENE
  • Benzene,1-fluoro-2-methyl-
CAS:
95-52-3
MF:
C7H7F
MW:
110.13
EINECS:
202-428-5
Product Categories:
  • Aryl Fluorinated Building Blocks
  • Building Blocks
  • C7-C8
  • Chemical Synthesis
  • Fluorinated Building Blocks
  • Halogenated Hydrocarbons
  • Aromatic Hydrocarbons (substituted) & Derivatives
  • Organics
  • Aryl
  • organofluorine compounds
  • Organic Building Blocks
  • Organic Fluorinated Building Blocks
  • Other Fluorinated Organic Building Blocks
  • alkyl Fluorine
  • C7
  • Halogenated Hydrocarbons
Mol File:
95-52-3.mol
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2-Fluorotoluene Chemical Properties

Melting point:
-62 °C (lit.)
Boiling point:
113-114 °C (lit.)
Density 
1.001 g/mL at 25 °C (lit.)
vapor density 
3.8 (vs air)
vapor pressure 
21 mm Hg ( 20 °C)
refractive index 
n20/D 1.473(lit.)
Flash point:
55 °F
storage temp. 
Store below +30°C.
form 
Liquid
Specific Gravity
1.001
color 
Clear colorless to slightly yellow
explosive limit
1.3%(V)
Water Solubility 
immiscible
Merck 
14,4180
BRN 
1853362
Dielectric constant
4.2199999999999998
LogP
2.73-2.74
CAS DataBase Reference
95-52-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-fluoro-2-methyl-(95-52-3)
EPA Substance Registry System
o-Fluorotoluene (95-52-3)
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Safety Information

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
16-26-33-36-37/39
RIDADR 
UN 2388 3/PG 2
WGK Germany 
3
RTECS 
XT2579000
Hazard Note 
Flammable/Irritant
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29036990
Toxicity
LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg

MSDS

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2-Fluorotoluene Usage And Synthesis

Chemical Properties

clear colorless to slightly yellow liquid

Uses

It is employed in organic synthesis.

General Description

A colorless liquid with an aromatic odor. May sink or float on water.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

2-Fluorotoluene is of generally low reactivity. Reacts with strong oxidizing agents and strong reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides [USCG, 1999].

Health Hazard

Inhalation of vapor may cause respiratory irritation. Prolonged and repeated vapor exposures may produce systemic toxic effects.

Purification Methods

Dry o-fluorotoluene with P2O5 or CaSO4 and fractionally distil it through a silvered vacuum-jacketed glass column with 1/8th-in glass helices. A high reflux ratio is necessary because of the closeness of the boiling points of the o-, m-and p-isomers [Potter & Saylor J Am Chem Soc 37 90 1951]. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]

2-Fluorotoluene Preparation Products And Raw materials

Preparation Products

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