Fluoro-benzoic acid series Fluorobenzonitrile series Fluorobenzaldehyde series Fluorophenyl methanol series Fluoroanisole series Fluoroaniline series Fluoro phenylacetic series Fluorophenol series Fluorophenyl boronic acid series Fluoronitrobenzene series Fluoropyridine series Potassium fluoroborate series Series fluorobenzyl alcohol Fluorotoluene series Fluoro isatin series Fluoroethane series Fluorine propane series
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Organic fluorine compound

Fluoro-benzoic acid series Fluorobenzonitrile series Fluorobenzaldehyde series Fluorophenyl methanol series Fluoroanisole series Fluoroaniline series Fluoro phenylacetic series Fluorophenol series Fluorophenyl boronic acid series Fluoronitrobenzene series Fluoropyridine series Potassium fluoroborate series Series fluorobenzyl alcohol Fluorotoluene series Fluoro isatin series Fluoroethane series Fluorine propane series
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In 1896, the synthesis of ethyl fluoride acetate marked the beginning of the study of organic fluorine chemistry, it has been exactly a century. In the meantime, several historic breakthrough has greatly promoted the development of organic fluorine chemistry, such as the 1930s the application of freon used in the refrigeration industry, the implementation of the Manhattan Project during World War II and the 1950s high physiological activity of the synthesis of 5-fluorine urea. China is rich in fluorine resources, it has proven reserves of fluorite about a quarter of the world's total reserves, but until the 1950s, fluorine chemistry in China is still a blank. At the end of 50s, due to changes in the international situation, China began to develop its own atomic energy technology, the need for a number of special fluoride materials, since then, the study of organic fluorine chemistry in China has been started. Shanghai Institute of organic chemistry, Chinese Academy of Sciences, due to the excellent work in the basic research of organic fluorine chemistry, has been hailed as the "fluorine chemistry of Shanghai" by the international fluorine chemical industry.

The organic fluorine compound, also known as fluorocarbon compounds, i.e. containing C-F bond in the molecular structure, such as tetrafluoroethylene (CF2 = CF2), all the hydrogen atoms in the hydrocarbon molecules replaced by fluorine atoms, which are called the whole fluorine compounds. Fluorine is the most electronegative, the highest degree of oxidation of atoms in the periodic table, and therefore less susceptible to oxidation cleavage fluoropolymer, and the radius of the fluorine atom is almost equal to half of the C-C bond, so the fluorine atom can be arranged closely around the carbon atom to form a barrier to the C-C bond to ensure its chemical stability. The bond energy of C-F bond is extremely high, so the organic fluorides have good thermal stability, chemical stability and oxidation resistance. There are many fluorine-containing compounds, such as halothane, anti-cancer drugs, fluorouracil, fluphenazine, haloperidol,etc.

Organic fluorine compounds can be broadly divided into three categories.
①The fluorine alkyl chloride, mainly used in refrigerants and aerosol (see Freon entry).
② Perfluorinated hydrocarbons and perfluorinated ethers, acids, tertiary amines, wherein the perfluoroalkanes having high chemical stability. Such as perfluoroheptane are lubricant which resistant to oxidation and high temperature; perfluoroolefins such as tetrafluoroethylene is monomer of PTFE; the saturated organic compounds of perfluorodecalin and perfluorinated tertiary amines emulsified from the white emulsion (known as white blood), successful as a blood substitute for clinical.
③ Fluorine-containing polymer can excellent high temperature, low temperature resistance, chemical corrosion. Such as PTFE known as the king of plastic commonly, and perfluoro rubber (called Viton) copolymerized by vinylidene fluoride and HFP, etc., widely used in national defense, aerospace, petroleum, chemicals, machinery and other sectors, such as Gordon month clothing fire-proof, corrosion-resistant pipes and containers, clothing, wear pads, sliding pads of road and rail and bridges, and gaskets etc..

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Structure:
Chemical Name:
2-Hydroxymethyl-3-methyl-4-(2,2,2-trifluoroethoxy)pyridine hydrochloride
CAS:
103577-66-8
MF:
C9H10F3NO2
Structure:
Chemical Name:
4-CYANO-3-FLUOROPHENYLBORONIC ACID
CAS:
843663-18-3
MF:
C7H5BFNO2
Structure:
Chemical Name:
2-Fluoro-5-bromobenzotrifluoride
CAS:
393-37-3
MF:
C7H3BrF4
Structure:
Chemical Name:
2-Bromo-3-fluorophenol
CAS:
443-81-2
MF:
C6H4BrFO
Structure:
Chemical Name:
3,4-Difluorophenylboronic acid
CAS:
168267-41-2
MF:
C6H5BF2O2
Structure:
Chemical Name:
2,4-Difluorophenylboronic acid
CAS:
144025-03-6
MF:
C6H5BF2O2
Structure:
Chemical Name:
2-Bromo-6-fluorotoluene
CAS:
1422-54-4
MF:
C7H6BrF
Structure:
Chemical Name:
2-Bromo-4-fluorotoluene
CAS:
1422-53-3
MF:
C7H6BrF
Structure:
Chemical Name:
4-Chloro-3-fluoronitrobenzene
CAS:
350-31-2
MF:
C6H3ClFNO2
Structure:
Chemical Name:
4-BROMO-2-FLUOROBENZENEBORONIC ACID
CAS:
216393-64-5
MF:
C6H5BBrFO2
Structure:
Chemical Name:
3,5-Difluorobenzoic acid
CAS:
455-40-3
MF:
C7H4F2O2
Structure:
Chemical Name:
3-Chloro-4-fluorobenzoic acid
CAS:
403-16-7
MF:
C7H4ClFO2
Structure:
Chemical Name:
4-Chloro-2-fluorophenylboronic acid
CAS:
160591-91-3
MF:
C6H5BClFO2
Structure:
Chemical Name:
4-Iodobenzotrifluoride
CAS:
455-13-0
MF:
C7H4F3I
Structure:
Chemical Name:
3,5-Difluorophenol
CAS:
2713-34-0
MF:
C6H4F2O
Structure:
Chemical Name:
2,3-DIFLUOROBENZOTRIFLUORIDE
CAS:
64248-59-5
MF:
C7H3F5
Structure:
Chemical Name:
4-Bromo-3-fluorophenol
CAS:
121219-03-2
MF:
C6H4BrFO
Structure:
Chemical Name:
4-AMINO-2-FLUOROPHENOL
CAS:
399-96-2
MF:
C6H6FNO
Structure:
Chemical Name:
2,3-Dichlorobenzotrifluoride
CAS:
54773-19-2
MF:
C7H3Cl2F3
Structure:
Chemical Name:
2,2-BIS(3-AMINOPHENYL)HEXAFLUOROPROPANE
CAS:
47250-53-3
MF:
C15H12F6N2
Structure:
Chemical Name:
1-BROMO-4-FLUORO-2-NITROBENZENE
CAS:
446-09-3
MF:
C6H3BrFNO2
Structure:
Chemical Name:
2-Chloro-4-fluoroaniline
CAS:
2106-02-7
MF:
C6H5ClFN
Structure:
Chemical Name:
3-Chloro-4-fluorobenzonitrile
CAS:
117482-84-5
MF:
C7H3ClFN
Structure:
Chemical Name:
Pentafluorophenol
CAS:
771-61-9
MF:
C6HF5O
Structure:
Chemical Name:
4-Chloro-2-fluoroaniline
CAS:
57946-56-2
MF:
C6H5ClFN
Structure:
Chemical Name:
2,5-Difluorobenzoic acid
CAS:
2991-28-8
MF:
C7H4F2O2
Structure:
Chemical Name:
2-Bromo-5-fluorobenzaldehyde
CAS:
94569-84-3
MF:
C7H4BrFO
Structure:
Chemical Name:
3,5-Difluorobenzyl alcohol
CAS:
79538-20-8
MF:
C7H6F2O
Structure:
Chemical Name:
2,3,4-TRIFLUOROPHENOL
CAS:
2822-41-5
MF:
C6H3F3O
Structure:
Chemical Name:
4-BROMO-2,3,5,6-TETRAFLUOROANILINE
CAS:
1998-66-9
MF:
C6H2BrF4N
Structure:
Chemical Name:
2,3,4,5-Tetrafluoroaniline
CAS:
5580-80-3
MF:
C6H3F4N
Structure:
Chemical Name:
4-Bromo-3-fluoroanisole
CAS:
408-50-4
MF:
C7H6BrFO
Structure:
Chemical Name:
2-Bromo-5-chlorobenzotrifluoride
CAS:
344-65-0
MF:
C7H3BrClF3
Structure:
Chemical Name:
2-Bromo-5-fluoroaniline
CAS:
1003-99-2
MF:
C6H5BrFN
Structure:
Chemical Name:
2-Nitrobenzotrifluoride
CAS:
384-22-5
MF:
C7H4F3NO2
Structure:
Chemical Name:
2-Aminobenzotrifluoride
CAS:
88-17-5
MF:
C7H6F3N
Structure:
Chemical Name:
2,5-Difluoronitrobenzene
CAS:
364-74-9
MF:
C6H3F2NO2
Structure:
Chemical Name:
2,3-Difluoroanisole
CAS:
134364-69-5
MF:
C7H6F2O
Structure:
Chemical Name:
2,3-Difluorophenylacetic acid
CAS:
145689-41-4
MF:
C8H6F2O2
Structure:
Chemical Name:
4-Bromobenzotrifluoride
CAS:
402-43-7
MF:
C7H4BrF3
Structure:
Chemical Name:
1-BROMO-3-FLUOROPROPANE
CAS:
352-91-0
MF:
C3H6BrF
Structure:
Chemical Name:
5-(TRIFLUOROMETHYL)ISATIN
CAS:
345-32-4
MF:
C9H4F3NO2
Structure:
Chemical Name:
4-Bromo-2,6-difluoroanisole
CAS:
104197-14-0
MF:
C7H5BrF2O
Structure:
Chemical Name:
5-BROMO-2-FLUOROANILINE
CAS:
2924-09-6
MF:
C6H5BrFN
Structure:
Chemical Name:
3-Carboxy-4-fluorophenylboronic acid
CAS:
872460-12-3
MF:
C7H6BFO4
Structure:
Chemical Name:
3,5-Difluorophenylboronic acid
CAS:
156545-07-2
MF:
C6H5BF2O2
Structure:
Chemical Name:
4-BROMO-3,5-DIFLUOROPHENOL
CAS:
130191-91-2
MF:
C6H3BrF2O
Structure:
Chemical Name:
2-Chloro-4-fluorobenzaldehyde
CAS:
84194-36-5
MF:
C7H4ClFO
Structure:
Chemical Name:
4-Bromo-3-nitrobenzotrifluoride
CAS:
349-03-1
MF:
C7H3BrF3NO2
Structure:
Chemical Name:
2-Bromo-4,6-difluorophenol
CAS:
98130-56-4
MF:
C6H3BrF2O
Structure:
Chemical Name:
2-Fluorophenol
CAS:
367-12-4
MF:
C6H5FO
Structure:
Chemical Name:
2-Amino-5-bromobenzotrifluoride
CAS:
445-02-3
MF:
C7H5BrF3N
Structure:
Chemical Name:
4-Chloro-2-fluorophenol
CAS:
348-62-9
MF:
C6H4ClFO
Structure:
Chemical Name:
4-AMINO-3-FLUOROBENZOIC ACID
CAS:
455-87-8
MF:
C7H6FNO2
Structure:
Chemical Name:
4-Chloro-2-fluorobenzoic acid
CAS:
446-30-0
MF:
C7H4ClFO2
Structure:
Chemical Name:
2,4-Difluoronitrobenzene
CAS:
446-35-5
MF:
C6H3F2NO2
Structure:
Chemical Name:
2-Bromo-5-fluoroanisole
CAS:
450-88-4
MF:
C7H6BrFO
Structure:
Chemical Name:
2-FLUORO-4-METHOXYANILINE
CAS:
458-52-6
MF:
C7H8FNO
Structure:
Chemical Name:
3-Amino-4-fluorophenol
CAS:
62257-16-3
MF:
C6H6FNO
Structure:
Chemical Name:
2,3,4-Trifluorobenzonitrile
CAS:
143879-80-5
MF:
C7H2F3N
Structure:
Chemical Name:
4-BENZYLOXY-2-FLUOROPHENYLBORONIC ACID
CAS:
166744-78-1
MF:
C13H12BFO3
Structure:
Chemical Name:
2-Chloro-5-nitrobenzotrifluoride
CAS:
777-37-7
MF:
C7H3ClF3NO2
Structure:
Chemical Name:
2,6-Dibromo-4-fluoroaniline
CAS:
344-18-3
MF:
C6H4Br2FN
Structure:
Chemical Name:
2-Bromo-5-fluorophenol
CAS:
147460-41-1
MF:
C6H4BrFO
Structure:
Chemical Name:
2,4-DIBROMO-6-FLUOROPHENOL
CAS:
576-86-3
MF:
C6H3Br2FO
Structure:
Chemical Name:
3,5-Difluoronitrobenzene
CAS:
2265-94-3
MF:
C6H3F2NO2
Structure:
Chemical Name:
2-FLUOROPHENYLBORONIC ACID
CAS:
1193-03-9
MF:
C6H6BFO2
Structure:
Chemical Name:
3-Amino-5-bromobenzotrifluoride
CAS:
54962-75-3
MF:
C7H5BrF3N
Structure:
Chemical Name:
4-Bromo-2,6-difluorobenzoic acid
CAS:
183065-68-1
MF:
C7H3BrF2O2
Structure:
Chemical Name:
3-Bromo-4-fluoroaniline
CAS:
656-64-4
MF:
C6H5BrFN
Structure:
Chemical Name:
3-Nitrobenzotrifluoride
CAS:
98-46-4
MF:
C7H4F3NO2
Structure:
Chemical Name:
2,2-Bis(4-aminophenyl)hexafluoropropane
CAS:
1095-78-9
MF:
C15H12F6N2
Structure:
Chemical Name:
3-Chloro-4,5-difluorobenzotrifluoride
CAS:
77227-99-7
MF:
C7H2ClF5
Structure:
Chemical Name:
3-Chloro-2-fluorobenzaldehyde
CAS:
85070-48-0
MF:
C7H4ClFO
Structure:
Chemical Name:
2,3-Difluorobenzoic acid
CAS:
4519-39-5
MF:
C7H4F2O2
Structure:
Chemical Name:
2-BROMO-6-CHLORO-4-FLUOROANILINE
CAS:
201849-14-1
MF:
C6H4BrClFN
Structure:
Chemical Name:
3,5-Dichloro-4-fluorobenzotrifluoride
CAS:
77227-81-7
MF:
C7H2Cl2F4
Structure:
Chemical Name:
3,5-Diaminobenzotrifluoride
CAS:
368-53-6
MF:
C7H7F3N2
Structure:
Chemical Name:
2-Chloro-4,5-difluorobenzoic acid
CAS:
110877-64-0
MF:
C7H3ClF2O2
Structure:
Chemical Name:
2-Chloro-6-fluorotoluene
CAS:
443-83-4
MF:
C7H6ClF
Structure:
Chemical Name:
3,5-Difluoroanisole
CAS:
93343-10-3
MF:
C7H6F2O
Structure:
Chemical Name:
Benzotrifluoride
CAS:
98-08-8
MF:
C7H5F3
Structure:
Chemical Name:
3-Bromobenzotrifluoride
CAS:
401-78-5
MF:
C7H4BrF3
Structure:
Chemical Name:
2-Amino-5-nitrobenzotrifluoride
CAS:
121-01-7
MF:
C7H5F3N2O2
Structure:
Chemical Name:
4'-TRIFLUOROMETHYLPHENYL ACETYLENE
CAS:
705-31-7
MF:
C9H5F3
Structure:
Chemical Name:
2-Fluorobenzotrifluoride
CAS:
392-85-8
MF:
C7H4F4
Structure:
Chemical Name:
2-Bromo-4-chloro-6-fluoroaniline
CAS:
195191-47-0
MF:
C6H4BrClFN
Structure:
Chemical Name:
4-Fluorobenzyl alcohol
CAS:
459-56-3
MF:
C7H7FO
Structure:
Chemical Name:
1-CHLORO-2-IODOTETRAFLUOROETHANE
CAS:
421-78-3
MF:
C2ClF4I
Structure:
Chemical Name:
3-METHYLBENZOTRIFLUORIDE
CAS:
401-79-6
MF:
C8H7F3
Structure:
Chemical Name:
3-(Trifluoromethyl)benzonitrile
CAS:
368-77-4
MF:
C8H4F3N
Structure:
Chemical Name:
2,4-DINITRO-5-FLUOROANILINE
CAS:
367-81-7
MF:
C6H4FN3O4
Structure:
Chemical Name:
2-BROMO-6-FLUOROANILINE
CAS:
65896-11-9
MF:
C6H5BrFN
Structure:
Chemical Name:
3,4-Difluoroaniline
CAS:
3863-11-4
MF:
C6H5F2N
Structure:
Chemical Name:
2-Bromo-4-fluoroaniline
CAS:
1003-98-1
MF:
C6H5BrFN
Structure:
Chemical Name:
3-Fluoro-4-aminobenzonitrile
CAS:
63069-50-1
MF:
C7H5FN2
Structure:
Chemical Name:
3,5-Difluorobenzonitrile
CAS:
64248-63-1
MF:
C7H3F2N
Structure:
Chemical Name:
4-Bromo-3-fluorobenzotrifluoride
CAS:
40161-54-4
MF:
C7H3BrF4
Structure:
Chemical Name:
5-Bromo-2-chlorobenzotrifluoride
CAS:
445-01-2
MF:
C7H3BrClF3
Structure:
Chemical Name:
2-CHLORO-5-FLUORONITROBENZENE
CAS:
345-17-5
MF:
C6H3ClFNO2