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2-Chlorobenzotrifluoride

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2-Chlorobenzotrifluoride Basic information

Product Name:
2-Chlorobenzotrifluoride
Synonyms:
  • CHLOROBENZOTRIFLUORIDE(O-)
  • 2-CHLOROBENZOTRIFLUOROIDE
  • o-Trifluoromethylphenyl
  • Toluene, o-chloro-alpha,alpha,alpha-trifluoro-
  • O-CHLORO(TRIFLUOROMETHYL)BENZENE
  • O-CHLOROBENZYLIDYNE TRIFLUORIDE
  • O-CHLOROBENZOTRIFLUORIDE
  • O-CHLORO-A,A,A-TRIFLUOROTOLUENE
CAS:
88-16-4
MF:
C7H4ClF3
MW:
180.55
EINECS:
201-805-1
Product Categories:
  • Chlorine Compounds
  • Fluorine Compounds
  • Aromatic Hydrocarbons (substituted) & Derivatives
Mol File:
88-16-4.mol
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2-Chlorobenzotrifluoride Chemical Properties

Melting point:
-7.4 °C
Boiling point:
152 °C(lit.)
Density 
1.379 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.456(lit.)
Flash point:
138 °F
storage temp. 
Flammables area
form 
clear liquid
color 
Colorless to Light yellow
Specific Gravity
1.379
explosive limit
1.7%(V)
Water Solubility 
<0.1 g/100 mL at 19.5 ºC
BRN 
510993
Exposure limits
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
Stability:
Stable. Flammable. Incompatible with strong oxidizing agents, strong bases.
CAS DataBase Reference
88-16-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-chloro-2-(trifluoromethyl)-(88-16-4)
EPA Substance Registry System
2-Chlorobenzotrifluoride (88-16-4)
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Safety Information

Hazard Codes 
Xi,F,Xn,N
Risk Statements 
10-36/37/38-22
Safety Statements 
26-36-36/37/39-16
RIDADR 
UN 2234 3/PG 3
WGK Germany 
3
RTECS 
XS9141000
Hazard Note 
Flammable/Irritant
TSCA 
T
HazardClass 
3
PackingGroup 
III
HS Code 
29036990

MSDS

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2-Chlorobenzotrifluoride Usage And Synthesis

Chemical Properties

Clear colourless to light yellow liquid

Uses

Dye intermediate, chemical intermediate, solvent, and dielectric fluid.

Purification Methods

Dry the trifluoride over CaSO4, and distil it at high reflux ratio through a silvered vacuum-jacketed glass column packed with one-eight inch glass helices [Potter & Saylor J Am Chem Soc 73 90 1951]. [Beilstein 5 H 302, 5 III 692, 5 IV 814.]

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