2-Fluorotoluene
- Product Name
- 2-Fluorotoluene
- CAS No.
- 95-52-3
- Chemical Name
- 2-Fluorotoluene
- Synonyms
- O-FLUOROTOLUENE;1-Fluoro-2-methylbenzene;FC6H4CH3;o-Fluortoluol;2-Fluortoluol;o-fluoro-toluen;2-FLUOROTOLUENE;2-fulorotoluene;o-Flouorotoluene;2-FLUOROTOLOUENE
- CBNumber
- CB8664172
- Molecular Formula
- C7H7F
- Formula Weight
- 110.13
- MOL File
- 95-52-3.mol
2-Fluorotoluene Property
- Melting point:
- -62 °C (lit.)
- Boiling point:
- 113-114 °C (lit.)
- Density
- 1.001 g/mL at 25 °C (lit.)
- vapor density
- 3.8 (vs air)
- vapor pressure
- 21 mm Hg ( 20 °C)
- refractive index
- n20/D 1.473(lit.)
- Flash point:
- 55 °F
- storage temp.
- Store below +30°C.
- form
- Liquid
- Specific Gravity
- 1.001
- color
- Clear colorless to slightly yellow
- explosive limit
- 1.3%(V)
- Water Solubility
- immiscible
- Merck
- 14,4180
- BRN
- 1853362
- Dielectric constant
- 4.2199999999999998
- InChI
- 1S/C7H7F/c1-6-4-2-3-5-7(6)8/h2-5H,1H3
- InChIKey
- MMZYCBHLNZVROM-UHFFFAOYSA-N
- SMILES
- Cc1ccccc1F
- LogP
- 2.73-2.74
- CAS DataBase Reference
- 95-52-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, 1-fluoro-2-methyl-(95-52-3)
- EPA Substance Registry System
- o-Fluorotoluene (95-52-3)
Safety
- Hazard Codes
- F,Xi
- Risk Statements
- 11-36/37/38
- Safety Statements
- 16-26-33-36-37/39
- RIDADR
- UN 2388 3/PG 2
- WGK Germany
- 3
- RTECS
- XT2579000
- Hazard Note
- Flammable/Irritant
- TSCA
- TSCA listed
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29036990
- Storage Class
- 3 - Flammable liquids
- Hazard Classifications
- Flam. Liq. 2
STOT SE 3 - Toxicity
- LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
N-Bromosuccinimide Price
- Product number
- F15323
- Product name
- 2-Fluorotoluene
- Purity
- ≥99%
- Packaging
- 100g
- Price
- $60.1
- Updated
- 2025/07/31
- Product number
- F15323
- Product name
- 2-Fluorotoluene
- Purity
- ≥99%
- Packaging
- 500g
- Price
- $146
- Updated
- 2025/07/31
- Product number
- F0039
- Product name
- 2-Fluorotoluene
- Purity
- >99.0%(GC)
- Packaging
- 25mL
- Price
- $16
- Updated
- 2025/07/31
- Product number
- F0039
- Product name
- 2-Fluorotoluene
- Purity
- >99.0%(GC)
- Packaging
- 500mL
- Price
- $86
- Updated
- 2025/07/31
- Product number
- 09-4310
- Product name
- o-Fluorotoluene, 99%
- Packaging
- 50g
- Price
- $31
- Updated
- 2024/03/01
2-Fluorotoluene Chemical Properties,Usage,Production
Chemical Properties
clear colorless to slightly yellow liquid
Uses
It is employed in organic synthesis.
General Description
A colorless liquid with an aromatic odor. May sink or float on water.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
2-Fluorotoluene is of generally low reactivity. Reacts with strong oxidizing agents and strong reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides [USCG, 1999].
Health Hazard
Inhalation of vapor may cause respiratory irritation. Prolonged and repeated vapor exposures may produce systemic toxic effects.
Synthesis
The halogen exchange method reacts aromatic compounds with alkali metal fluorides (e.g., CsF and KF, etc.) and substituent groups, allowing the fluorine atom to replace other halogen groups (e.g., chlorine). The reaction method of halogen exchange between inorganic halides and between organic halides is known as the Finkelstein method. It is one of the most widely used methods for synthesizing fluoroaromatic compounds in industrial production, and has been one of the more active areas in the synthesis of fluoroaromatic compounds in recent years. Halogen exchange method is the main method with industrialized application value, characterized by low price of raw materials, easy to obtain and good selectivity, and in the reaction process can not use fluoroboric acid, hydrogen fluoride and other highly toxic reagents, in general, relatively environmentally friendly and safe, in line with the trend of the development of pharmaceutical pesticides nowadays. The disadvantage is that its reaction conditions are relatively harsh, requiring reaction at higher temperatures and under the condition of excess potassium fluoride, and also requiring the use of non-protonic inert reagents as solvents, and need to be carried out under the condition of anhydrous.
Purification Methods
Dry o-fluorotoluene with P2O5 or CaSO4 and fractionally distil it through a silvered vacuum-jacketed glass column with 1/8th-in glass helices. A high reflux ratio is necessary because of the closeness of the boiling points of the o-, m-and p-isomers [Potter & Saylor J Am Chem Soc 37 90 1951]. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]
2-Fluorotoluene Preparation Products And Raw materials
Raw materials
Preparation Products
2-Fluorotoluene Suppliers
- Tel
- 13376001577
- 615731430@qq.com
- Country
- China
- ProdList
- 325
- Advantage
- 58
- Tel
- 15366451979
- sales@huahongchem.com
- Country
- China
- ProdList
- 24
- Advantage
- 58
- Tel
- 18615658326
- 18615658326@163.com
- Country
- China
- ProdList
- 58
- Advantage
- 58
- Tel
- 18853316981
- 1214127295@qq.com
- Country
- China
- ProdList
- 204
- Advantage
- 58
- Tel
- 18652911584
- 381854775@qq.com
- Country
- China
- ProdList
- 310
- Advantage
- 58
- Tel
- 18815338815
- dexinhuaxue@163.com
- Country
- China
- ProdList
- 149
- Advantage
- 58
- Tel
- 0455-7669909 18746673231
- 2035411054@qq.com
- Country
- China
- ProdList
- 17
- Advantage
- 58
- Tel
- 17887358129
- lvfu@163.cn
- Country
- China
- ProdList
- 29
- Advantage
- 58
- Tel
- 4006356688 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40228
- Advantage
- 62
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
View Lastest Price from 2-Fluorotoluene manufacturers
- Product
- 2-Fluorotoluene 95-52-3
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-21
- Product
- 2-Fluorotoluene 95-52-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 50mg
- Purity
- 99%HPLC
- Supply Ability
- 2000tons
- Release date
- 2020-01-08
- Product
- 2-Fluorotoluene 95-52-3
- Price
- US $10.00/Kg/Bag
- Min. Order
- 1Kg/Bag
- Purity
- 99%
- Supply Ability
- 20 Tons
- Release date
- 2021-11-19