2-Fluorobenzotrifluoride

Product Name: 2-Fluorobenzotrifluoride
CAS No.: 392-85-8
Chemical Name: 2-Fluorobenzotrifluoride
Synonyms: 1-FLUORO-2-(TRIFLUOROMETHYL)BENZENE;uorobenzotrifL;2-tetrafluorotoluene;2-Fluorobenzotrifluo;2-Fluorobezotrifluoride;2-FLUOROBENZOTRIFLUORIDE;o-fluorotrifluorotoluene;O-FLUOROBENZOTRIFLUORIDE;2-Fluoro trifluoroMethyl;à,à,à,2-tetrafluorotoluene
CBNumber: CB1313699
Molecular Formula: C7H4F4
Formula Weight: 164.1
MOL File: 392-85-8.mol

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2-Fluorobenzotrifluoride Property

Melting point:: -49°C
Boiling point:: 114-115 °C750 mm Hg(lit.)
Density: 1.293 g/mL at 25 °C(lit.)
refractive index: n20/D 1.406(lit.)
Flash point:: 64 °F
storage temp.: Sealed in dry,2-8°C
form: clear liquid
Specific Gravity: 1.31
color: Colorless to Light yellow to Light orange
BRN: 2046638
InChI: InChI=1S/C7H4F4/c8-6-4-2-1-3-5(6)7(9,10)11/h1-4H
InChIKey: BGVGHYOIWIALFF-UHFFFAOYSA-N
SMILES: C1(F)=CC=CC=C1C(F)(F)F
CAS DataBase Reference: 392-85-8(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-fluoro-2-(trifluoromethyl)-(392-85-8)
EPA Substance Registry System: Benzene, 1-fluoro-2-(trifluoromethyl)- (392-85-8)

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Safety

Hazard Codes: F,Xi
Risk Statements: 11-36/37/38
Safety Statements: 16-26-33-24/25-7/9
RIDADR: UN 1993 3/PG 2
WGK Germany: 3
Hazard Note: Flammable/Irritant
TSCA: T
HazardClass: 3
PackingGroup: II
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: F0389
Product name: 2-Fluorobenzotrifluoride
Purity: >98.0%(GC)
Packaging: 5g
Price: $24
Updated: 2025/07/31

TCI Chemical

Product number: F0389
Product name: 2-Fluorobenzotrifluoride
Purity: >98.0%(GC)
Packaging: 25g
Price: $61
Updated: 2025/07/31

TRC

Product number: F598960
Product name: 1-Fluoro-2-trifluoromethylbenzene
Packaging: 1g
Price: $55
Updated: 2021/12/16

Oakwood

Product number: 001617
Product name: 2-Fluorobenzotrifluoride
Purity: 99%
Packaging: 25g
Price: $12
Updated: 2021/12/16

Apolloscientific

Product number: PC7596
Product name: 2-Fluorobenzotrifluoride
Purity: 97%
Packaging: 1Kg
Price: $87
Updated: 2021/12/16

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2-Fluorobenzotrifluoride Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

2-Fluorobenzotrifluoride was used in the synthesis of 2,2′-bis(trifluoromethylphenoxy)biphenyl via nucleophilic aromatic substitution reaction with 2,2′-biphenol.

Synthesis

98-08-8

402-44-8

401-80-9

392-85-8

393-38-4

General procedure: In a FEP or PFA reactor equipped with a PTFE-lined magnetic stirring bar and connected to a gas scrubber bottle, substituted benzene (0.95-1.10 mmol), 1,1,1,3,3-pentafluorobutane (2 ml per ml C6H5R), and BF3-Et2O (1.3-1.5 mmol per mmol C6H5R) were added. The mixture was stirred at 0-5 °C (ice bath) for 10-15 min, followed by batchwise addition of XeF2 (1.2-1.3 mmol per mmol C6H5R). After each addition, the mixture was stirred at 22-25 °C for 3-5 min and cooled again. After the addition was completed, the dark solution was continued to be stirred at 22-25 °C for 15-30 min. Subsequently, 10% aqueous KHCO3 solution was added and the upper organic layer was separated and filtered through a short column equipped with silica gel (40-60 μm) and finally dried with magnesium sulfate. The solution was analyzed by 19F NMR and GC/MS. The major products are listed in the table and other products are as follows (GC/MS data).

References

[1] Russian Journal of Organic Chemistry, 2016, vol. 52, # 10, p. 1400 - 1407
[2] Zh. Org. Khim., 2016, vol. 52, # 10, p. 1412 - 1419,8

2-Fluorobenzotrifluoride Preparation Products And Raw materials

Raw materials

Sodium nitrite o-Toluidine

Preparation Products

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2-Fluorobenzotrifluoride Suppliers

Americas 1 Belgium 1 Canada 2 China 257 Europe 4 France 2 Germany 3 India 8 Italy 1 Japan 5 Russia 1 Slovakia 1 South Korea 1 Switzerland 2 Ukraine 1 United Kingdom 19 United States 36 Global 345

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View Lastest Price from 2-Fluorobenzotrifluoride manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 2-Fluorobenzotrifluoride 392-85-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KGS
Release date: 2025-07-01

Hebei Chuanghai Biotechnology Co., Ltd

Product: 2-Fluorobenzotrifluoride 392-85-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 mt
Release date: 2024-12-04

Jinan Finer Chemical Co., Ltd

Product: 2-Fluorobenzotrifluoride 392-85-8
Price: US $0.00/Kg/Drum
Min. Order: 1KG
Purity: 99%
Supply Ability: 200mt/year
Release date: 2021-07-22

392-85-8, 2-Fluorobenzotrifluoride Related Search:

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392-85-8

392-89-8

Organic Building Blocks

Building Blocks

C7

Aryl

Halogenated Hydrocarbons

Aromatic Hydrocarbons (substituted) & Derivatives

Benzene series

Miscellaneous

Trifluoromethylbenzene serise

bc0001