METHYL 3-CYANO-4-METHOXYBENZOATE
Uses- Product Name
- METHYL 3-CYANO-4-METHOXYBENZOATE
- CAS No.
- 25978-74-9
- Chemical Name
- METHYL 3-CYANO-4-METHOXYBENZOATE
- Synonyms
- METHYL 3-CYANO-4-METHOXYBENZOATE;3-Cyano-4-methoxybenzoic acid methyl ester;methyl 3-cyano-4-methoxybenzoate - [M85982];Benzoic acid, 3-cyano-4-methoxy-, methyl ester
- CBNumber
- CB0144973
- Molecular Formula
- C10H9NO3
- Formula Weight
- 191.18
- MOL File
- 25978-74-9.mol
METHYL 3-CYANO-4-METHOXYBENZOATE Property
- Melting point:
- 124 °C
- Boiling point:
- 339.7±27.0 °C(Predicted)
- Density
- 1.20±0.1 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- Appearance
- White to yellow Solid
- BRN
- 2374769
- InChI
- InChI=1S/C10H9NO3/c1-13-9-4-3-7(10(12)14-2)5-8(9)6-11/h3-5H,1-2H3
- InChIKey
- RYJSFYBJYKFNCF-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=C(OC)C(C#N)=C1
- CAS DataBase Reference
- 25978-74-9
Safety
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36/37/39
- RIDADR
- 3439
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 2926907090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H331Toxic if inhaled
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- M338278
- Product name
- Methyl3-Cyano-4-methoxybenzoate
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FC55139
- Product name
- 3-Cyano-4-methoxybenzoic acid methyl ester
- Packaging
- 5G
- Price
- $60
- Updated
- 2021/12/16
- Product number
- FC55139
- Product name
- 3-Cyano-4-methoxybenzoic acid methyl ester
- Packaging
- 10g
- Price
- $90
- Updated
- 2021/12/16
- Product number
- 4637-1-U8
- Product name
- Methyl 3-cyano-4-methoxybenzoate
- Packaging
- 1g
- Price
- $96
- Updated
- 2021/12/16
- Product number
- FC55139
- Product name
- 3-Cyano-4-methoxybenzoic acid methyl ester
- Packaging
- 25g
- Price
- $175
- Updated
- 2021/12/16
METHYL 3-CYANO-4-METHOXYBENZOATE Chemical Properties,Usage,Production
Uses
Methyl 3-Cyano-4-methoxybenzoate is a useful research chemical.
Synthesis
35450-37-4
25978-74-9
General procedure for the synthesis of methyl 3-cyano-4-methoxybenzoate from methyl 3-bromo-4-methoxybenzoate: to a solution of methyl 3-bromo-4-methoxybenzoate (1.1 g, 4.4 mmol) in dimethylformamide (10 mL) was added cuprous cyanide (1.2 g, 13.2 mmol). The reaction mixture was heated to 140 °C and maintained for 6 hours. After the reaction was completed, it was cooled to room temperature and diluted by adding ethyl acetate (25 mL). The organic phase was washed with saturated sodium chloride solution, dried over anhydrous sodium sulfate and concentrated under reduced pressure. The crude product was purified by fast column chromatography (eluent: petroleum ether/ethyl acetate=10:1) to afford methyl 3-cyano-4-methoxybenzoate (662 mg, 79% yield) as a white solid.
References
[1] Patent: CN106146504, 2016, A. Location in patent: Paragraph 0219; 0220; 0221; 0224; 0225
METHYL 3-CYANO-4-METHOXYBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL 3-CYANO-4-METHOXYBENZOATE Suppliers
- Tel
- --
- Fax
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- info@chemodex.com
- Country
- Switzerland
- ProdList
- 1549
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View Lastest Price from METHYL 3-CYANO-4-METHOXYBENZOATE manufacturers
- Product
- Methyl 3-cyano-4-methoxybenzoate 25978-74-9
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- kgs
- Release date
- 2023-01-03
- Product
- METHYL 3-CYANO-4-METHOXYBENZOATE 25978-74-9
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-10