Hexyl acetate
- Product Name
- Hexyl acetate
- CAS No.
- 142-92-7
- Chemical Name
- Hexyl acetate
- Synonyms
- C2;ACETIC ACID HEXYL ESTER;N-HEXYL ACETATE;HEXYL ETHANOATE;1-Hexyl acetate;ACETIC ACID N-HEXYL ESTER;FEMA 2565;Hexylacetat;ACETATE C-6;Hexvl acetate
- CBNumber
- CB0161882
- Molecular Formula
- C8H16O2
- Formula Weight
- 144.21
- MOL File
- 142-92-7.mol
Hexyl acetate Property
- Melting point:
- -80 °C (lit.)
- Boiling point:
- 168-170 °C (lit.)
- Density
- 0.87 g/mL at 25 °C (lit.)
- vapor pressure
- 5 hPa (20 °C)
- FEMA
- 2565 | HEXYL ACETATE
- refractive index
- n20/D 1.409(lit.)
- Flash point:
- 99 °F
- storage temp.
- Store below +30°C.
- solubility
- 0.4g/l
- form
- Liquid
- color
- Clear colorless to pale yellow
- Odor
- at 10.00 % in dipropylene glycol. fruity green apple banana sweet
- Odor Type
- fruity
- Odor Threshold
- 0.0018ppm
- Water Solubility
- immiscible
- JECFA Number
- 128
- BRN
- 1747138
- Dielectric constant
- 4.4199999999999999
- LogP
- 3.3 at 30℃
- CAS DataBase Reference
- 142-92-7(CAS DataBase Reference)
- NIST Chemistry Reference
- Hexyl ethanoate(142-92-7)
- EPA Substance Registry System
- Acetic acid, hexyl ester (142-92-7)
Safety
- Risk Statements
- 10
- Safety Statements
- 16
- RIDADR
- UN 3272 3/PG 3
- WGK Germany
- 1
- RTECS
- AI0875000
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29153990
- Hazardous Substances Data
- 142-92-7(Hazardous Substances Data)
- Toxicity
- LD50 orally in Rabbit: 36100 mg/kg LD50 dermal Rabbit > 5000 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P273Avoid release to the environment.
N-Bromosuccinimide Price
- Product number
- W256528
- Product name
- Hexyl acetate
- Purity
- natural, ≥98%, FCC, FG
- Packaging
- 100g
- Price
- $83
- Updated
- 2024/03/01
- Product number
- W256528
- Product name
- Hexyl acetate
- Purity
- natural, ≥98%, FCC, FG
- Packaging
- 1kg
- Price
- $222
- Updated
- 2024/03/01
- Product number
- W256528
- Product name
- Hexyl acetate
- Purity
- natural, ≥98%, FCC, FG
- Packaging
- 4kg
- Price
- $720
- Updated
- 2024/03/01
- Product number
- W256501
- Product name
- Hexyl acetate
- Purity
- ≥98%, FCC, FG
- Packaging
- 1kg
- Price
- $76.5
- Updated
- 2024/03/01
- Product number
- W256501
- Product name
- Hexyl acetate
- Purity
- ≥98%, FCC, FG
- Packaging
- 5kg
- Price
- $198
- Updated
- 2024/03/01
Hexyl acetate Chemical Properties,Usage,Production
Description
Hexyl acetate has a pleasant fruity odor and bittersweet taste suggestive of pear. May be synthesized from n-hexyl alcohol and excess acetic anhydride at the boil or with an excess of acetic acid in the presence of concentrated sulfuric acid.
Chemical Properties
clear colorless to pale yellowish liquid
Chemical Properties
Hexyl Acetate is a liquid with a sweet-fruity, pear-like odor. It is present in a number of fruits and alcoholic beverages and is used in fruit aroma compositions.
Chemical Properties
Hexyl acetate has a pleasant fruity, apple, cherry, pear, floral odor and bittersweet taste suggestive of pear.
Occurrence
Reported found in fruital aromas (e.g., Fragaria vesca) and essential oils. Also reported found in apple, apricot, banana, sweet cherry, citrus peel oils and juices, blueberry, black currants, guava, grapes, melon, peach, pear, raspberry, blackberry, strawberry, peas, sauerkraut, rye bread, cheeses, roasted beef, beer, rum, cognac, whiskies, cider, sherry, grape wines, coffee, tea, soybean, olive, passion fruit, beans, starfruit, mango, cauliflower, pear and apple brandy, quince, origanum, lovage leaf, corn oil, mangosteen (Garcia mangostana), Bourbon vanilla, clary sage, nectarine, naranjilla fruit, Chinese quince and chamomile oil.
Uses
n-Hexyl acetate exhibits antimicrobial activity and can be used to improve the safety of minimally processed fruits. It is a fruity smelling fluid used as flavoring agent or in perfumes. It is a green leaf volatile from cabbage Brassica oleracea var. capitata L. It is used as plasticizers.
Uses
Hexyl acetate was used to study the activity of diamondback moth sex pheromone and larval frass volatiles, as well as green leaf volatiles from cabbage, on the natural enemies of the pest.
Uses
Hexyl Acetate is a flavouring agent due to its fruity odor and it is naturally present in many fruits and alcoholic beverages.
Production Methods
n-Hexyl acetate is prepared from n-hexyl alcohol and excess
acetic anhydride or with an excess of acetic acid and
concentrated sulfuric acid . Its is also prepared from
primary and sec-hexyl alcohols .
It is produced by Aldrich Chemical Corp., Milwaukee, WI,
and Penta Manufacturing Co., Fairfield, NJ .
Preparation
From n-hexyl alcohol and excess acetic anhydride at the boil or with an excess of acetic acid in the presence of concentrated sulfuric acid
Definition
ChEBI: The acetate ester of hexan-1-ol.
Aroma threshold values
Detection: 2 to 480 ppb
Taste threshold values
Taste characteristics at 15 ppm: fruity, green, fresh, sweet, banana peel, apple and pear.
Synthesis Reference(s)
Tetrahedron Letters, 18, p. 3263, 1977 DOI: 10.1016/S0040-4039(01)83213-5
General Description
A colorless liquid with a mild sweet odor. Flash point 113°F. A moderate fire risk. Inhalation may cause adverse effects. Almost insoluble in water, soluble in alcohol and Propylene glycol, miscible with oils. When heated to high temperatures emits acrid smoke and fumes. Used as a solvent and as a propellant in aerosols.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
Hexyl acetate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Hazard
Combustible.
Health Hazard
May be harmful by inhalation, ingestion, or skin absorption. May cause irritation.
Fire Hazard
Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flash back. Container explosion may occur under fire conditions. Forms explosive mixtures in air.
Flammability and Explosibility
Flammable
Biochem/physiol Actions
Hexyl acetate has antimicrobial activity and can be used to improve the safety of minimally processed fruits. Hexyl acetate is a fruity smelling fluid used as flavoring agent or in perfumes. Hexyl acetate is a green leaf volatile from cabbage Brassica oleracea var. capitata L.
Hexyl acetate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Hexyl acetate manufacturers
- Product
- Hexyl acetate 142-92-7
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 100tons
- Release date
- 2023-09-25
- Product
- Hexyl Acetate 142-92-7
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- Hexyl Acetate 142-92-7
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09