TITANIUM NITRIDE Property

Melting point:

2930 °C (lit.)

Boiling point:

0°C

Density 

5.24 g/mL at 25 °C (lit.)

RTECS 

XR2230000

Flash point:

0°C

solubility 

it is soluble in aqua regia on boiling.

form 

Powder

Specific Gravity

5.24

color 

Yellow

Resistivity

21.7 (ρ/μΩ.cm)

Water Solubility 

Soluble in aqua regain. Partly soluble in water.

Crystal Structure

Cubic

Stability:

Stable. Incompatible with strong acids.

InChIKey

NRTOMJZYCJJWKI-UHFFFAOYSA-N

LogP

0

CAS DataBase Reference

25583-20-4(CAS DataBase Reference)

EPA Substance Registry System

Titanium nitride (TiN) (25583-20-4)

Safety

Safety Statements 

22-24/25

RIDADR 

UN3178

WGK Germany 

3

TSCA 

Yes

HazardClass 

4.1

PackingGroup 

III

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Hazard statements

H220Extremely flammable gas

H319Causes serious eye irritation

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

TITANIUM NITRIDE Chemical Properties,Usage,Production

Uses

Titanium (IV) nitride (TiN) is a hard brittle metal that is used in alloys, to manufacture semiconducting instruments, as cements, and as an abrasive.

Chemical Properties

gold or brown powder

Chemical Properties

Tin is a soft, white, silvery metal that is insoluble in water. Tin metal is used to line cans for food, beverages, and aerosols. It is present in brass, bronze, pewter, and some soldering materials. Tin can combine with other chemicals to form various compounds. When tin is combined with chlorine, sulfur, or oxygen, it is called an inorganic tin compound. Inorganic tin compounds are found in small amounts in the earth’s crust. They are also present in toothpaste, perfumes, soaps, coloring agents, food additives, and dyes. Tin when combined with carbon forms organotin compounds. These compounds are used in making plastics, food packages, plastic pipes, pesticides, paints, wood preservatives, and rodent (rats and mice) repellants. Organic tin compounds stick to soil, sediment, and particles in water. Humans are usually exposed to tin at far less than 1 ppm in air and water. The amounts in air and water near hazardous waste sites could be higher. The most common use for tin coating is for edge retention and corrosion resistance on machine tooling, such as drill bits and milling cutters, often improving their lifetime by a factor of three or more.

Physical properties

Bronze powder. Transition temperature 4.2 K. Corrosion resistant to molten metals such as Al, Pb, Mg, Zn, Cd, and Bi. Corroded by molten Na, Rb, Ti, V, Cr, Mn, Sn, Ni, Cu, Fe, and Co. Dissolved by boiling aqua regia, decomposed by boiling alkalis evolving NH₃.

Uses

As protective coating for cutting tools; in diffusion barriers for microelectronic devices; as crucibles in metal smelting; as a gold-colored surface for jewelry. In high-performance ceramic materials. As a coating for orthopedic and dental implants.

Uses

Titanium nitride (TiN) is an extremely hard ceramic material, often used as a coating on Ti alloys, steel, carbide and Al components to improve the substrate’s surface properties. Applied as a thin coating (less than 5 μm), TiN is used to harden and protect cutting and sliding surfaces, for decorative purposes due to its gold appearance and as a non-toxic exterior for medical implants.

Uses

Titanium Nitride (TiN), a gold-colored coating, is an excellent general purpose coating for protecting a wide variety of tools from wear. TiN coated tools are used for machining high alloy steels and low alloy steels at medium and high cutting speeds. Tool life is three to five times longer than uncoated HSS and carbide end mills.

Health Hazard

Inhalation breathing in, oral eating or drinking, or dermal exposure skin contact to some organotin compounds has been shown to cause harmful effects in humans, but the main effect will depend on the particular organotin compound. There have been reports of skin and eye irritation, respiratory irritation, gastrointestinal effects, and neurological problems in humans exposed for a short period of time to high amounts of certain organotin compounds. Some neurological problems have persisted for years after the poisoning occurred. Lethal cases have been reported following ingestion of very high amounts. Studies in animals have shown that certain organotins mainly affect the immune system, but a different type primarily affects the nervous system. Yet, there are some organotins that exhibit very low toxicity. Exposure of pregnant rats and mice to some organotin compounds has reduced fertility and caused stillbirth, but scientists are still not sure whether this occurs only with doses that are also toxic to the mother. Some animal studies also suggest that the reproductive organs of males may be affected

Flammability and Explosibility

Non flammable

Industrial uses

Titanium nitride, TiN, is a light-brown powderwith a cubic lattice crystal structure. Sinteredbars are extremely hard and brittle, with a hardnessabove Mohs 9 and a melting point of2950°C. It is not attacked by nitric, sulfuric, orhydrochloric acid, and is resistant to oxidationat high temperatures. In recent years, titaniumnitridecoatings have been used to markedlyextend the life of tool-steel cutters and formingtools. The coatings, golden in color, are depositedby chemical or physical vapor deposition.Aluminum nitride, AlN, when molded intoshapes and sintered, forms a dense, nonporousstructure with a hardness of Mohs 6. It resiststhe action of molten iron or silicon to 1704°C,and molten aluminum to 1427°C, but isattacked by oxygen and carbon dioxide at760°C. At least 1% oxygen causes AlN propertiesto deteriorate rapidly.