(R)-MOP

Product Name: (R)-MOP
CAS No.: 145964-33-6
Chemical Name: (R)-MOP
Synonyms: (R)-MOP;R-MOP >=94%;(R)-(+)-MOP;98% (R)-MOP;99% (R)-MOP;(R)-(+)-2-(DiphenyL;phosphino)-2'-methoxy-1,1'-binaphthyL;(S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(R)-(+)-2-DIPHENYLPHOSPHINO-2'-METHOXY-1,1'-BINAPHTHYL
CBNumber: CB0180962
Molecular Formula: C33H25OP
Formula Weight: 468.52
MOL File: 145964-33-6.mol

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(R)-MOP Property

Melting point:: 177-179°C
alpha: +67° ±2° (c 1, toluene)
Boiling point:: 584.1±38.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: almost transparency in Toluene
form: Powder
color: white
optical activity: [α]20/D +94°, c = 0.5 in chloroform
Sensitive: air sensitive
CAS DataBase Reference: 145964-33-6(CAS DataBase Reference)

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3
HS Code: 2931.90.6000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: D2774
Product name: (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl
Purity: >98.0%(GC)
Packaging: 1g
Price: $699
Updated: 2024/03/01

TCI Chemical

Product number: D2774
Product name: (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl
Purity: >98.0%(GC)
Packaging: 100mg
Price: $144
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1775
Product name: (R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP
Packaging: 100mg
Price: $99
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1775
Product name: (R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP
Packaging: 500mg
Price: $396
Updated: 2024/03/01

TRC

Product number: R600000
Product name: (R)-MOP
Packaging: 100mg
Price: $220
Updated: 2021/12/16

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(R)-MOP Chemical Properties,Usage,Production

Uses

(R)-MOP is used as a catalyst in the preparation of chiral tetrahydrobenzofuranone alkylideneboronates and oxindoles. Also used as a catalyst in the total synthesis of Oseltamivir Phosphate (O701000); an orally active inhibitor of influenza virus neuraminidase and an antiviral drug.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Ligand used in palladium-catalyzed asymmetric hydrosilylation of olefins, palladium-catalyzed reduction of allylic esters, rhodium-catalyzed asymmetric addition reactions, and asymmetric amination reactions catalyzed by copper(I) complexes.

Reactions

1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols.
2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters.
3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes.
4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins.
5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction.

General Description

R-MOP is a phosphine ligand with a bis-naphthalene backbone.

(R)-MOP Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-MOP Suppliers

Americas 1 Belgium 2 China 82 Europe 1 France 1 Germany 2 India 2 Japan 3 Norway 1 Switzerland 1 United Kingdom 1 United States 12 Global 109

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
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Fax: 86-21-61259102
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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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Daicel Chiral Technologies (China)CO.,LTD

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TOKYO CHEMICAL INDUSTRY CO., LTD.

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TCI Europe

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TCI AMERICA

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Country: Americas
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View Lastest Price from (R)-MOP manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (R)-MOP 145964-33-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: (R)-(+)-2-Diphenylphosphino-2"-methoxy-1,1"-binaphthyl 145964-33-6
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (R)-MOP 145964-33-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-08-08

145964-33-6, (R)-MOPRelated Search:

MOP (S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl (R)-(+)-2-DIPHENYLPHOSPHINO-2'-METHOXY-1,1'-BINAPHTHYL 8-MOP MOP 4-MOP,5-MOP 1,1'-BINAPHTHYL 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine MOP ANTI-MOP3, HUMAN, 15AA NEAR CT ANTI-MOP3 MOP3, HUMAN, 15AA NEAR CT MOUSE ANTI-8-METHOXYPSORALEN (8MOP) MONOADDUCTS ANTI-MOP3, 22AA NEAR NT MOP4, HUMAN, 15AA INTERNAL DOMAIN ANTI-MOP4, HUMAN, 15AA INTERNAL DOMAIN MOP3, 22AA NEAR NT ANTI-MOP4

R-MOP >=94%

[(R)-2'-Methoxy[1,1'-binaphthalen]-2-yl]diphenylphosphine,99%e.e.

(R)-(+)-2-DIPHENYLPHOSPHINO-2'-METHOXY-1,1'-BINAPHTHYL

(S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL

(R)-(+)-MOP

(R)-MOP

(S)-(-)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL

(S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL

(R)-(+)-2-(diphenylphosphino)-2’-methoxy-21,1’-binaphthyl(r-mop)

(R)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl (R)-MOP

(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl,99%(R)-MOP

(R)-(2'-Methoxy[1,1'-binaphthalen]-2-yl)diphenyl-phosphine

98% (R)-MOP

[(1R)-2'-METHOXY[1,1'-BINAPHTHALEN]-2-YL]DIPHENYL-PHOSPHINE

(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl&gt

(R)-(+)-2-(DiphenyL

99% (R)-MOP

phosphino)-2'-methoxy-1,1'-binaphthyL

Phosphine, [(1R)-2'-methoxy[1,1'-binaphthalen]-2-yl]diphenyl-

(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl

(R)-(2’-Methoxy-[1,1’-binaphthalen]-2-yl)diphenylphosphine

145964-33-6

Chiral Phosphine

API intermediates

Chiral Reagents