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2-(Diphenylphosphino)-biphenyl

Product Name
2-(Diphenylphosphino)-biphenyl
CAS No.
13885-09-1
Chemical Name
2-(Diphenylphosphino)-biphenyl
Synonyms
2-Diphenylphosphine benzene;2-(DiphenylphosphiNA)-biphenyl;2-(Diphenylphosphino)-biphenyl;biphenyl-2-yldiphenylphosphine;o-Phenylphenyldiphenylphosphane;2-Biphenylyl(diphenyl)phosphine;2-(Diphenylphosphino)biphenyl >2-(Diphenylphosphino)-biphenyl,98%;2-(Diphenylphosphino)-1,1'-biphenyl;1,1'-biphenyl]-2-yldiphenylphosphine
CBNumber
CB01856079
Molecular Formula
C24H19P
Formula Weight
338.38
MOL File
13885-09-1.mol
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2-(Diphenylphosphino)-biphenyl Property

Melting point:
80.0 to 86.0 °C
Boiling point:
473.2±24.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
Solid
color 
White to Almost white
Water Solubility 
Slightly soluble in water.
CAS DataBase Reference
13885-09-1
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Safety

HS Code 
2931.90.9051
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D4688
Product name
2-(Diphenylphosphino)biphenyl
Purity
>98.0%(GC)
Packaging
1g
Price
$35
Updated
2025/07/31
TRC
Product number
D492738
Product name
2-(Diphenylphosphinobiphenyl
Packaging
100mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD140367
Product name
2-(Diphenylphosphino)-biphenyl
Packaging
2g
Price
$70
Updated
2021/12/16
AK Scientific
Product number
J97841
Product name
2-(Diphenylphosphino)biphenyl
Packaging
25g
Price
$120
Updated
2021/12/16
ChemScene
Product number
CS-W003792
Product name
2-(Diphenylphosphino)biphenyl
Packaging
25g
Price
$99
Updated
2021/12/16
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2-(Diphenylphosphino)-biphenyl Chemical Properties,Usage,Production

Uses

2-(Diphenylphosphino)biphenyl is used as an organic chemical synthesis intermediate.

Uses

2-(Diphenylphosphino)biphenyl as ligand for suzuki reaction.

Synthesis

2113-51-1

829-85-6

13885-09-1

General procedure for the synthesis of 2-(diphenylphosphino)-biphenyl from 2-iodobiphenyl and diphenylphosphine: MCM-41-3N-Pd(0) catalyst (21 mg, 0.01 mmol), KOAc (1.5 mmol), and 2-iodobiphenyl (1.0 mmol if solid) were placed in a 20 mL Schlenk tube that had been pre oven-dried. The reaction vessel was evacuated and displaced three times with argon. Subsequently, 2-iodobiphenyl (1.0 mmol, if liquid), diphenylphosphine (1.2 mmol) and DMAc (1 mL) were added via syringe under argon protection. The reaction mixture was stirred at 130°C for 3 hours. After the reaction was completed, the mixture was cooled to room temperature, diluted with CH2Cl2 (20 mL) and filtered.The MCM-41-3N-Pd(0) catalyst was washed with distilled water (2 × 5 mL) and ethanol (2 × 5 mL) for next use. The filtrate was concentrated under vacuum and the residue was purified by fast column chromatography on silica gel to afford the target product 2-(diphenylphosphino)-biphenyl.

References

[1] Organic Letters, 2003, vol. 5, # 13, p. 2315 - 2318
[2] Applied Organometallic Chemistry, 2018, vol. 32, # 8,
[3] Journal of Organometallic Chemistry, 2018, vol. 866, p. 50 - 58

2-(Diphenylphosphino)-biphenyl Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(Diphenylphosphino)-biphenyl Suppliers

Americas 1 Belgium 1 Canada 1 China 173 Europe 1 France 1 Germany 4 India 4 Japan 2 The Netherlands 1 United Kingdom 2 United States 21 Global 212
Aokbio Inc
Tel
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Fax
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Country
Canada
ProdList
54
Advantage
58
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View Lastest Price from 2-(Diphenylphosphino)-biphenyl manufacturers

Hebei Fengjia New Material Co., Ltd
Product
2-(Diphenylphosphino)-biphenyl 13885-09-1
Price
US $3.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10000
Release date
2024-08-16
Hebei Chuanghai Biotechnology Co., Ltd
Product
2-(Diphenylphosphino)-biphenyl 13885-09-1
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 mt
Release date
2024-11-25
XINXIANG RUNYU MATERIAL CO., LTD.
Product
2-(Diphenylphosphino)-biphenyl 13885-09-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
0.98
Supply Ability
500KG
Release date
2021-11-29

13885-09-1, 2-(Diphenylphosphino)-biphenylRelated Search:

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