ChemicalBook > CAS DataBase List > 2-(Diphenylphosphino)-biphenyl
2-(Diphenylphosphino)-biphenyl
- Product Name
- 2-(Diphenylphosphino)-biphenyl
- CAS No.
- 13885-09-1
- Chemical Name
- 2-(Diphenylphosphino)-biphenyl
- Synonyms
- 2-Diphenylphosphine benzene;2-(DiphenylphosphiNA)-biphenyl;2-(Diphenylphosphino)-biphenyl;biphenyl-2-yldiphenylphosphine;o-Phenylphenyldiphenylphosphane;2-Biphenylyl(diphenyl)phosphine;2-(Diphenylphosphino)biphenyl >2-(Diphenylphosphino)-biphenyl,98%;2-(Diphenylphosphino)-1,1'-biphenyl;1,1'-biphenyl]-2-yldiphenylphosphine
- CBNumber
- CB01856079
- Molecular Formula
- C24H19P
- Formula Weight
- 338.38
- MOL File
- 13885-09-1.mol
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2-(Diphenylphosphino)-biphenyl Property
- Melting point:
- 80.0 to 86.0 °C
- Boiling point:
- 473.2±24.0 °C(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- form
- Solid
- color
- White to Almost white
- Water Solubility
- Slightly soluble in water.
- CAS DataBase Reference
- 13885-09-1
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Safety
- HS Code
- 2931.90.9051
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
TCI Chemical
- Product number
- D4688
- Product name
- 2-(Diphenylphosphino)biphenyl
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $35
- Updated
- 2025/07/31
TRC
- Product number
- D492738
- Product name
- 2-(Diphenylphosphinobiphenyl
- Packaging
- 100mg
- Price
- $75
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FD140367
- Product name
- 2-(Diphenylphosphino)-biphenyl
- Packaging
- 2g
- Price
- $70
- Updated
- 2021/12/16
AK Scientific
- Product number
- J97841
- Product name
- 2-(Diphenylphosphino)biphenyl
- Packaging
- 25g
- Price
- $120
- Updated
- 2021/12/16
ChemScene
- Product number
- CS-W003792
- Product name
- 2-(Diphenylphosphino)biphenyl
- Packaging
- 25g
- Price
- $99
- Updated
- 2021/12/16
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2-(Diphenylphosphino)-biphenyl Chemical Properties,Usage,Production
Uses
2-(Diphenylphosphino)biphenyl is used as an organic chemical synthesis intermediate.
Uses
2-(Diphenylphosphino)biphenyl as ligand for suzuki reaction.
Synthesis
2113-51-1
829-85-6
13885-09-1
General procedure for the synthesis of 2-(diphenylphosphino)-biphenyl from 2-iodobiphenyl and diphenylphosphine: MCM-41-3N-Pd(0) catalyst (21 mg, 0.01 mmol), KOAc (1.5 mmol), and 2-iodobiphenyl (1.0 mmol if solid) were placed in a 20 mL Schlenk tube that had been pre oven-dried. The reaction vessel was evacuated and displaced three times with argon. Subsequently, 2-iodobiphenyl (1.0 mmol, if liquid), diphenylphosphine (1.2 mmol) and DMAc (1 mL) were added via syringe under argon protection. The reaction mixture was stirred at 130°C for 3 hours. After the reaction was completed, the mixture was cooled to room temperature, diluted with CH2Cl2 (20 mL) and filtered.The MCM-41-3N-Pd(0) catalyst was washed with distilled water (2 × 5 mL) and ethanol (2 × 5 mL) for next use. The filtrate was concentrated under vacuum and the residue was purified by fast column chromatography on silica gel to afford the target product 2-(diphenylphosphino)-biphenyl.
References
[1] Organic Letters, 2003, vol. 5, # 13, p. 2315 - 2318
[2] Applied Organometallic Chemistry, 2018, vol. 32, # 8,
[3] Journal of Organometallic Chemistry, 2018, vol. 866, p. 50 - 58
2-(Diphenylphosphino)-biphenyl Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-(Diphenylphosphino)-biphenyl manufacturers
Hebei Fengjia New Material Co., Ltd
- Product
- 2-(Diphenylphosphino)-biphenyl 13885-09-1
- Price
- US $3.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10000
- Release date
- 2024-08-16
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- 2-(Diphenylphosphino)-biphenyl 13885-09-1
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-25
XINXIANG RUNYU MATERIAL CO., LTD.
- Product
- 2-(Diphenylphosphino)-biphenyl 13885-09-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 0.98
- Supply Ability
- 500KG
- Release date
- 2021-11-29
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