4-IODO-3-NITROTOLUENE
- Product Name
- 4-IODO-3-NITROTOLUENE
- CAS No.
- 5326-39-6
- Chemical Name
- 4-IODO-3-NITROTOLUENE
- Synonyms
- 3-nitro-4-iodotoluol;4-IODO-3-NITROTOLUENE;3-nitro-4-iodotoluene;4-Iodo-3-nitrotoluene,97%;4-IODO-3-NITROTOLUENE 97%;4-Iodo-3-nitrotoluene, 98.5%;4-METHYL-2-NITRO IODO BENZENE;1-Iodo-2-nitro-4-methylbenzene;1-IODO-4-METHYL-2-NITROBENZENE;Benzene, 1-iodo-4-methyl-2-nitro-
- CBNumber
- CB0190703
- Molecular Formula
- C7H6INO2
- Formula Weight
- 263.03
- MOL File
- 5326-39-6.mol
4-IODO-3-NITROTOLUENE Property
- Melting point:
- 53-56 °C(lit.)
- Boiling point:
- 111°C 1mm
- Density
- 1.8886 (estimate)
- Flash point:
- 110 °C
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- soluble in Methanol
- form
- Glistening Powder
- color
- Orange-brown
- CAS DataBase Reference
- 5326-39-6(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-20/21/22
- Safety Statements
- 26-36-36/37/39-22
- WGK Germany
- 3
- HazardClass
- IRRITANT
- HS Code
- 29049090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 540447
- Product name
- 4-Iodo-3-nitrotoluene
- Purity
- 98%
- Packaging
- 5g
- Price
- $60.2
- Updated
- 2023/06/20
- Product number
- I1022
- Product name
- 4-Iodo-3-nitrotoluene
- Packaging
- 1G
- Price
- $27
- Updated
- 2025/07/31
- Product number
- I1022
- Product name
- 4-Iodo-3-nitrotoluene
- Packaging
- 5G
- Price
- $105
- Updated
- 2025/07/31
- Product number
- B448778
- Product name
- 1-Iodo-4-methyl-2-nitrobenzene
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 4754-H-01
- Product name
- 4-Iodo-3-nitrotoluene
- Purity
- 95%
- Packaging
- 1g
- Price
- $15
- Updated
- 2021/12/16
4-IODO-3-NITROTOLUENE Chemical Properties,Usage,Production
Chemical Properties
orange-brown glistening powder
Uses
4-Iodo-3-nitrotoluene may be used in the preparation of:
- 3-cyano-4-iodotoluene
- 4,6′-dimethyl-2 ,2′-dinitrobiphenyl
- bis(2-nitro-4-methylphenyl) sulfide
General Description
4-Iodo-3-nitrotoluene can be prepared from 4-amino-3-nitrotoluene according to the procedure described by Carlin and Foltz.
Synthesis
27329-27-7
5326-39-6
General procedure for the synthesis of 4-iodo-3-nitrotoluene from 4-methyl-2-nitrobenzoic acid: To a Silak reaction tube equipped with a magnetic stirrer, 6.2 mg of silver sulfate (Ag2SO4), 21.8 mg of copper acetate (Cu(OAc)2), 12.5 mg of 2,9-dimethyl-1,10-o-phenanthroline (as a ligand), 36.2 mg 4 -methyl-2-nitrobenzoic acid (as raw material) and 45 mg of sodium iodide (NaI), dissolved in 4 mL of dimethyl sulfoxide (DMSO). The reaction mixture was heated to 160°C under oxygen atmosphere and the reaction was stirred for 24 hours. Upon completion of the reaction, the reaction was quenched by the addition of distilled water and extracted three times with ethyl acetate (10 mL each time). The organic phases were combined and concentrated under reduced pressure to give 27.9 mg of 4-iodo-3-nitrotoluene (target product) in 53% yield.
References
[1] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803
[2] Patent: CN107325002, 2017, A. Location in patent: Paragraph 0091
[3] Organic and Biomolecular Chemistry, 2018, vol. 16, # 30, p. 5416 - 5421
4-IODO-3-NITROTOLUENE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-IODO-3-NITROTOLUENE manufacturers
- Product
- 4-IODO-3-NITROTOLUENE 5326-39-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-07-04
- Product
- 4-IODO-3-NITROTOLUENE 5326-39-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2025-03-14
- Product
- 4-IODO-3-NITROTOLUENE 5326-39-6
- Price
- US $0.00-0.00/g
- Min. Order
- 1g
- Purity
- 98%
- Supply Ability
- 2000kg
- Release date
- 2023-07-12